On the preference of liquid-metal embrittlement along high-angle grain-boundaries in galvanized steels

IF 5.3 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Yuki Ikeda , Seungchang Han , Theophilus Wallis , Reza Darvishi Kamachali , Robert Maaß
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引用次数: 0

Abstract

Focusing on the early stages of liquid-metal embrittlement (LME) of Zinc (Zn) coated advanced high-strength steels, we show that the Zn infiltration path prior to grain-boundary decohesion and therefore cracking distinctly follows high-angle grain boundaries (HAGBs). This selective transport prior to LME-induced microcracking rationalizes the experimentally observed post-mortem cracking along martensitic HAGBs. We discuss the selective Zn transport and GB-weakening in terms of an misorientation-angle dependent atomic density and diffusivity, and its effect on GB-segregation.

Abstract Image

镀锌钢高角晶界液态金属脆化的偏好
重点研究了锌涂层高级高强钢的液态金属脆(LME)的早期阶段,我们发现在晶界脱黏之前,锌的渗透路径明显遵循高角度晶界(HAGBs)。这种在lme诱导的微裂之前的选择性传输使实验观察到的马氏体HAGBs死后开裂合理化。我们从原子密度和扩散系数的角度讨论了锌的选择性输运和gb -弱化,以及它对gb -偏析的影响。
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来源期刊
Scripta Materialia
Scripta Materialia 工程技术-材料科学:综合
CiteScore
11.40
自引率
5.00%
发文量
581
审稿时长
34 days
期刊介绍: Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.
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