Emerging techniques and scenarios of scanning electrochemical microscopy for the characterization of electrocatalytic reactions

Abstract

To fulfill the evergrowing energy consumption demands and the pursuit of sustainable and renewable energy, electrocatalytic reactions such as the water electrocatalysis reaction, the O₂ reduction reaction, the N₂ reduction reaction (NRR), the CO₂ reduction reaction (CO₂RR), etc., have drawn a lot of attention. Scanning electrochemical microscopy (SECM) is a powerful technique for in situ surface characterization, providing critical information about the local reactivity of electrocatalysts and unveiling key information about the reaction mechanisms, which are essential for the rational design of novel electrocatalysts. There has been a growing trend of SECM-based studies in electrocatalytic reactions, with a major focus on water splitting and O₂ reduction reactions, and relying mostly on conventional SECM techniques. Recently, novel operation modes of SECM have emerged, adding new features to the functionality of SECM and successfully expanding the scope of SECM to other electrocatalytic reactions, i.e., the NRR, the NO₃⁻ reduction reaction (NO₃RR), the CO₂RR and so on, as well as more complicated electrolysis systems, i.e. gas diffusion electrodes. In this perspective, we summarized recent progress in the development of novel SECM techniques and recent SECM-based research studies on the NRR, NO₃RR, CO₂RR, and so on, where quantitative information on the reaction mechanism and catalyst reactivity was uncovered through SECM. The development of novel SECM techniques and the application of these techniques can provide new insights into the reaction mechanisms of diverse electrocatalytic reactions as well as the in situ characterization of electrocatalysts, facilitating the pursuit of sustainable and renewable energy.