Preparation and application of cardanol ether-based anionic–nonionic surfactant

IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED
Hong Chen, Aijun Hao, Baowei Zhu, Jingyu Zhang, Xiao Wu, Lei Yuan
{"title":"Preparation and application of cardanol ether-based anionic–nonionic surfactant","authors":"Hong Chen,&nbsp;Aijun Hao,&nbsp;Baowei Zhu,&nbsp;Jingyu Zhang,&nbsp;Xiao Wu,&nbsp;Lei Yuan","doi":"10.1002/jsde.12835","DOIUrl":null,"url":null,"abstract":"<p>Using cardanol polyoxyethylene ether, maleic anhydride, and sodium bisulfite as main raw materials, a new type of surfactant, sodium dicardanol polyoxyethylene sulfosuccinate anionic–nonionic surfactant was synthesized. The effects of reaction temperature, material ratio, and catalyst dosage on esterification reaction were investigated by single factor and orthogonal experiment method, and the reaction conditions of esterification and sulfonation were optimized. Fourier infrared spectroscopy, liquid chromatography-mass spectrometry and proton nuclear magnetic resonance were employed to determine the target product. The surface tension of obtained sodium dicardanol polyoxyethylene sulfosuccinate <i>γ</i><sub>CMC</sub> was measured as 34.54 mM/m, and critical micelle concentration was 1.61 × 10<sup>−4</sup> mol/L. The surface tension of sodium dicardanol polyoxyethylene sulfosuccinate under different pH and salty environments was further tested, and it was found that sodium dicardanol polyoxyethylene sulfosuccinate showed certain resistance to acid-base and salt conditions. The cleaning agent for aluminum was prepared using sodium dicardanol polyoxyethylene sulfosuccinate, exhibiting promising performance characterized by its non-corrosive and environmentally friendly properties.</p>","PeriodicalId":17083,"journal":{"name":"Journal of Surfactants and Detergents","volume":"28 3","pages":"675-686"},"PeriodicalIF":1.6000,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surfactants and Detergents","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jsde.12835","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0

Abstract

Using cardanol polyoxyethylene ether, maleic anhydride, and sodium bisulfite as main raw materials, a new type of surfactant, sodium dicardanol polyoxyethylene sulfosuccinate anionic–nonionic surfactant was synthesized. The effects of reaction temperature, material ratio, and catalyst dosage on esterification reaction were investigated by single factor and orthogonal experiment method, and the reaction conditions of esterification and sulfonation were optimized. Fourier infrared spectroscopy, liquid chromatography-mass spectrometry and proton nuclear magnetic resonance were employed to determine the target product. The surface tension of obtained sodium dicardanol polyoxyethylene sulfosuccinate γCMC was measured as 34.54 mM/m, and critical micelle concentration was 1.61 × 10−4 mol/L. The surface tension of sodium dicardanol polyoxyethylene sulfosuccinate under different pH and salty environments was further tested, and it was found that sodium dicardanol polyoxyethylene sulfosuccinate showed certain resistance to acid-base and salt conditions. The cleaning agent for aluminum was prepared using sodium dicardanol polyoxyethylene sulfosuccinate, exhibiting promising performance characterized by its non-corrosive and environmentally friendly properties.

Abstract Image

腰果酚醚阴离子-非离子表面活性剂的制备及应用
以腰果酚聚氧乙烯醚、马来酸酐和亚硫酸氢钠为主要原料,合成了一种新型表面活性剂——双腰果酚聚氧乙烯磺酸丁二酸钠阴离子-非离子表面活性剂。通过单因素试验和正交试验研究了反应温度、物料配比、催化剂用量对酯化反应的影响,优化了酯化和磺化的反应条件。采用傅里叶红外光谱法、液相色谱-质谱法和质子核磁共振法测定目标产物。测定得到的双二酚聚氧乙烯磺酸琥珀酸钠γCMC的表面张力为34.54 mM/m,临界胶束浓度为1.61 × 10−4 mol/L。进一步测试了双二酚聚氧乙烯磺基琥珀酸钠在不同pH和盐环境下的表面张力,发现双二酚聚氧乙烯磺基琥珀酸钠对酸碱和盐条件具有一定的耐受性。以双二酚聚氧乙烯磺酸琥珀酸钠为原料制备了铝清洗剂,该清洗剂具有无腐蚀、环保等特点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Surfactants and Detergents
Journal of Surfactants and Detergents 工程技术-工程:化工
CiteScore
3.80
自引率
6.20%
发文量
68
审稿时长
4 months
期刊介绍: Journal of Surfactants and Detergents, a journal of the American Oil Chemists’ Society (AOCS) publishes scientific contributions in the surfactants and detergents area. This includes the basic and applied science of petrochemical and oleochemical surfactants, the development and performance of surfactants in all applications, as well as the development and manufacture of detergent ingredients and their formulation into finished products.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信