Sodium nonylcyclohexanol ethoxylate sulfate-based strategy for remediating dye-contaminated soil with low surfactant adsorption

IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED
Xueyi Hu, Yongjin Zhang, Fei Qian, Jianyi Liu, Guiju Zhang, Yongmei Xia
{"title":"Sodium nonylcyclohexanol ethoxylate sulfate-based strategy for remediating dye-contaminated soil with low surfactant adsorption","authors":"Xueyi Hu,&nbsp;Yongjin Zhang,&nbsp;Fei Qian,&nbsp;Jianyi Liu,&nbsp;Guiju Zhang,&nbsp;Yongmei Xia","doi":"10.1002/jsde.12822","DOIUrl":null,"url":null,"abstract":"<p>Surfactant-assisted soil cleaning has been considered as a promising technology for remediating of dye-contaminated soil, but is significantly impeded by limitations such as the adsorption or precipitation of surfactants in soil. To take the advantage of effective remediation of anionic surfactant and lower adsorption of nonionic surfactant, a remediation system has been developed in this study for soil contaminated with model dyes methyl orange and alizarin red, employing a designed anionic-nonionic surfactant known as sodium nonylcyclohexanol ethoxylates sulfate (NCEO<sub>5</sub>S) and a commercial surfactant—sodium alkyl alcohol ethoxylate sulfate (AES). Using simple wash, the elution efficiency on highly-contaminated soil (methyl orange and alizarin red) reached up to 94.34% and 97.66%, respectively, at 25°C in 24 h with 1 wt% of surfactant solution. Electrostatic repulsion noticeably mitigates surfactant adsorption on the soil surface. The low adsorption of surfactants on the eluted soil surface was characterized with SEM-EDS and thermogravimetric analysis. The kinetics of surfactant-enhanced dyes desorption from contaminated soil follow the Elovich equation. The findings will be benefit for developing eco-friendly surfactant systems to clean-up dyes-contaminated soils while minimizing surfactant adsorption.</p>","PeriodicalId":17083,"journal":{"name":"Journal of Surfactants and Detergents","volume":"28 3","pages":"651-662"},"PeriodicalIF":1.6000,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surfactants and Detergents","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jsde.12822","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0

Abstract

Surfactant-assisted soil cleaning has been considered as a promising technology for remediating of dye-contaminated soil, but is significantly impeded by limitations such as the adsorption or precipitation of surfactants in soil. To take the advantage of effective remediation of anionic surfactant and lower adsorption of nonionic surfactant, a remediation system has been developed in this study for soil contaminated with model dyes methyl orange and alizarin red, employing a designed anionic-nonionic surfactant known as sodium nonylcyclohexanol ethoxylates sulfate (NCEO5S) and a commercial surfactant—sodium alkyl alcohol ethoxylate sulfate (AES). Using simple wash, the elution efficiency on highly-contaminated soil (methyl orange and alizarin red) reached up to 94.34% and 97.66%, respectively, at 25°C in 24 h with 1 wt% of surfactant solution. Electrostatic repulsion noticeably mitigates surfactant adsorption on the soil surface. The low adsorption of surfactants on the eluted soil surface was characterized with SEM-EDS and thermogravimetric analysis. The kinetics of surfactant-enhanced dyes desorption from contaminated soil follow the Elovich equation. The findings will be benefit for developing eco-friendly surfactant systems to clean-up dyes-contaminated soils while minimizing surfactant adsorption.

Abstract Image

壬基环己醇乙氧基硫酸钠对低表面活性剂吸附的染料污染土壤的修复策略
表面活性剂辅助土壤净化被认为是一种很有前途的修复染料污染土壤的技术,但由于表面活性剂在土壤中的吸附或沉淀等限制而受到严重阻碍。为了充分利用阴离子表面活性剂对甲基橙和西芹红模型染料的有效修复和非离子表面活性剂的低吸附性,本研究采用设计的阴离子-非离子表面活性剂壬基环己醇乙氧基硫酸盐钠(NCEO5S)和工业表面活性剂烷基醇乙氧基酸钠(AES),建立了甲基橙和西芹红模型染料土壤的修复体系。采用简单水洗法,在25℃、1 wt%的表面活性剂溶液条件下,24 h对高污染土壤(甲基橙和素红)的洗脱效率分别达到94.34%和97.66%。静电斥力明显减轻表面活性剂在土壤表面的吸附。用SEM-EDS和热重分析表征了表面活性剂在洗脱土壤表面的低吸附性。表面活性剂增强染料从污染土壤中解吸的动力学遵循Elovich方程。研究结果将有助于开发环保型表面活性剂体系,以清除染料污染的土壤,同时减少表面活性剂的吸附。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Surfactants and Detergents
Journal of Surfactants and Detergents 工程技术-工程:化工
CiteScore
3.80
自引率
6.20%
发文量
68
审稿时长
4 months
期刊介绍: Journal of Surfactants and Detergents, a journal of the American Oil Chemists’ Society (AOCS) publishes scientific contributions in the surfactants and detergents area. This includes the basic and applied science of petrochemical and oleochemical surfactants, the development and performance of surfactants in all applications, as well as the development and manufacture of detergent ingredients and their formulation into finished products.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信