{"title":"Sodium nonylcyclohexanol ethoxylate sulfate-based strategy for remediating dye-contaminated soil with low surfactant adsorption","authors":"Xueyi Hu, Yongjin Zhang, Fei Qian, Jianyi Liu, Guiju Zhang, Yongmei Xia","doi":"10.1002/jsde.12822","DOIUrl":null,"url":null,"abstract":"<p>Surfactant-assisted soil cleaning has been considered as a promising technology for remediating of dye-contaminated soil, but is significantly impeded by limitations such as the adsorption or precipitation of surfactants in soil. To take the advantage of effective remediation of anionic surfactant and lower adsorption of nonionic surfactant, a remediation system has been developed in this study for soil contaminated with model dyes methyl orange and alizarin red, employing a designed anionic-nonionic surfactant known as sodium nonylcyclohexanol ethoxylates sulfate (NCEO<sub>5</sub>S) and a commercial surfactant—sodium alkyl alcohol ethoxylate sulfate (AES). Using simple wash, the elution efficiency on highly-contaminated soil (methyl orange and alizarin red) reached up to 94.34% and 97.66%, respectively, at 25°C in 24 h with 1 wt% of surfactant solution. Electrostatic repulsion noticeably mitigates surfactant adsorption on the soil surface. The low adsorption of surfactants on the eluted soil surface was characterized with SEM-EDS and thermogravimetric analysis. The kinetics of surfactant-enhanced dyes desorption from contaminated soil follow the Elovich equation. The findings will be benefit for developing eco-friendly surfactant systems to clean-up dyes-contaminated soils while minimizing surfactant adsorption.</p>","PeriodicalId":17083,"journal":{"name":"Journal of Surfactants and Detergents","volume":"28 3","pages":"651-662"},"PeriodicalIF":1.6000,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surfactants and Detergents","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jsde.12822","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
Surfactant-assisted soil cleaning has been considered as a promising technology for remediating of dye-contaminated soil, but is significantly impeded by limitations such as the adsorption or precipitation of surfactants in soil. To take the advantage of effective remediation of anionic surfactant and lower adsorption of nonionic surfactant, a remediation system has been developed in this study for soil contaminated with model dyes methyl orange and alizarin red, employing a designed anionic-nonionic surfactant known as sodium nonylcyclohexanol ethoxylates sulfate (NCEO5S) and a commercial surfactant—sodium alkyl alcohol ethoxylate sulfate (AES). Using simple wash, the elution efficiency on highly-contaminated soil (methyl orange and alizarin red) reached up to 94.34% and 97.66%, respectively, at 25°C in 24 h with 1 wt% of surfactant solution. Electrostatic repulsion noticeably mitigates surfactant adsorption on the soil surface. The low adsorption of surfactants on the eluted soil surface was characterized with SEM-EDS and thermogravimetric analysis. The kinetics of surfactant-enhanced dyes desorption from contaminated soil follow the Elovich equation. The findings will be benefit for developing eco-friendly surfactant systems to clean-up dyes-contaminated soils while minimizing surfactant adsorption.
期刊介绍:
Journal of Surfactants and Detergents, a journal of the American Oil Chemists’ Society (AOCS) publishes scientific contributions in the surfactants and detergents area. This includes the basic and applied science of petrochemical and oleochemical surfactants, the development and performance of surfactants in all applications, as well as the development and manufacture of detergent ingredients and their formulation into finished products.