Depositional environment and redox conditions of the Moncorvo Ironstone – Unveiling the evolution of ironstones under Rheic Ocean influence

Abstract

Ironstones, as key archives of past marine environments, provide invaluable insights into Paleozoic history. Their mineralogy may reflect the physical-chemical conditions of the environment and the nature of available sediments. This study focuses on the Moncorvo Ironstone, a Lower-Middle Ordovician deposit formed during the opening of the Rheic Ocean. Here, we use an integrated approach combining sedimentology, petrology, and geochemistry to constrain the depositional settings and the redox landscape associated with the ironstone deposition. The Moncorvo Ironstone present some unusual characteristics, such as the lack of ooids, an uncommon mineralogy, and a stratigraphic thickness that can reach over >45 m, a remarkable feature for an ironstone. Our investigation reveals that this iron-rich sequence is distributed in two distinct marine environments: an inner shelf and a middle to distal shelf. Each environment has a unique mineral assemblage. Despite the influence of metamorphism and deformation, evidence suggests that much of the mineralogy and texture of this deposit still preserve characteristics of the original sediments. Finally, our findings, alongside a careful assessment of the mineralogy of other ironstones of similar age, suggest a strong stratification of the Rheic Ocean throughout the Early and Middle Ordovician.