Ammonium Salts as Convenient Ammonia Surrogates in the Willgerodt Reaction

IF 0.9 4区化学 Q4 CHEMISTRY, ORGANIC

Russian Journal of Organic Chemistry Pub Date : 2025-05-07 DOI:10.1134/S1070428024603273

E. A. Kvetkin, A. V. Sokolov

引用次数: 0

Abstract

A novel solvent-free modification of the Willgerodt reaction is proposed. It employs elemental sulfur and ammonium salts as safe and convenient surrogates of ammonia on a solid carrier. The reaction involving a combination of ammonium carbonate and aluminum oxide afforded arylacetamides in 48 to 85% yields.

Abstract Image

查看原文本刊更多论文

铵盐在Willgerodt反应中作为方便的氨替代物

提出了一种新的无溶剂改性Willgerodt反应。它采用单质硫和铵盐作为固体载体上氨的安全、方便的替代品。碳酸铵和氧化铝的反应产生芳基乙酰酰胺的收率为48% ~ 85%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.