{"title":"Enhanced microwave performance of nano-TiO2 modified lithium ferrites for high-power applications","authors":"Mingchao Yang, Lijun Jia, Zhihao Chen, Hongwei Li, Wei Xiang, Xuening Han, Huaiwu Zhang","doi":"10.1016/j.jeurceramsoc.2025.117483","DOIUrl":null,"url":null,"abstract":"<div><div>To meet the application requirements of high-power microwave devices, the effects of anatase nano-TiO<sub>2</sub> doping on the high-power withstanding capability, and microwave loss of lithium ferrites were investigated. The results revealed that an increased proportion of fine grains played a critical role in enhancing spin-wave linewidth (Δ<em>H</em><sub><em>k</em></sub>). The Curie temperature rose with increasing doping amount (<em>x</em>), which was attributed to the precipitation of the Bi-enriched ferrite phase. In particular, when <em>x</em> = 0.35, the sample exhibited high spin-wave linewidth (Δ<em>H</em><sub><em>k</em></sub> = 14.8 Oe) and low dielectric loss (tan<em>δ</em><sub><em>ε</em></sub> = 2.31 ×10<sup>−4</sup>), alongside a significant reduction in ferromagnetic resonance linewidth (Δ<em>H</em> = 88 Oe). Leveraging these properties, a classic high-power latching phase shifter was designed. The device achieved large phase shift (>358 °), low insertion loss (<0.84 dB), and small voltage standing wave ratio (<1.23). These excellent performances highlight the promising prospects of nano-TiO<sub>2</sub> modified lithium ferrites in high-power microwave device applications.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"45 13","pages":"Article 117483"},"PeriodicalIF":5.8000,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The European Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0955221925003036","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
To meet the application requirements of high-power microwave devices, the effects of anatase nano-TiO2 doping on the high-power withstanding capability, and microwave loss of lithium ferrites were investigated. The results revealed that an increased proportion of fine grains played a critical role in enhancing spin-wave linewidth (ΔHk). The Curie temperature rose with increasing doping amount (x), which was attributed to the precipitation of the Bi-enriched ferrite phase. In particular, when x = 0.35, the sample exhibited high spin-wave linewidth (ΔHk = 14.8 Oe) and low dielectric loss (tanδε = 2.31 ×10−4), alongside a significant reduction in ferromagnetic resonance linewidth (ΔH = 88 Oe). Leveraging these properties, a classic high-power latching phase shifter was designed. The device achieved large phase shift (>358 °), low insertion loss (<0.84 dB), and small voltage standing wave ratio (<1.23). These excellent performances highlight the promising prospects of nano-TiO2 modified lithium ferrites in high-power microwave device applications.
期刊介绍:
The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.