Hybrid nanofluids based on WSe2-WO3 and a siloxane-based fluid with application in concentrated solar power

IF 5.3 2区 化学 Q2 CHEMISTRY, PHYSICAL
Saray Gragera , Paloma Martínez-Merino , Juan Jesús Gallardo , Iván Carrillo-Berdugo , Desireé De los Santos , María Gragera , Rodrigo Alcántara , Javier Navas
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Abstract

Improving the efficiency of renewable energies to meet the growing demand for energy is one of the main goals of the research community. In this sense, concentrated solar power plants are a research line of interest at the present time. Therefore, in this work, hybrid nanofluids were prepared based on WSe2-WO3 nanosheets synthesized in our laboratory and a silicon oil-based fluid. These were widely characterized to determine whether the efficiency of the heat transfer processes occurring in this kind of plants can be improved. Thus, temporal physical stability was analysed, the nanofluids reaching a stability after several days that was maintained for over 40 days. Once stable, measurements were taken of the properties of interest of the nanofluids, namely density, surface tension, dynamic viscosity, isobaric specific heat and thermal conductivity. The density, surface tension and dynamic viscosity values for the nanofluids did not change significantly with respect to the base fluid. Their isobaric specific heat was improved by 5 %, while their thermal conductivity increased by about 6 %. All the properties measured were used to estimate a figure of merit for the application of nanofluids in concentrating solar power plants. Enhancements of about 19 % were found for two nanofluids, suggesting they are a promising option for use as heat transfer fluids in CSP-PTC plants.

Abstract Image

基于WSe2-WO3和硅氧烷的混合纳米流体在聚光太阳能中的应用
提高可再生能源的效率以满足日益增长的能源需求是研究界的主要目标之一。从这个意义上说,聚光太阳能发电厂是目前的研究热点。因此,本研究在实验室合成的WSe2-WO3纳米片和硅油基流体的基础上制备了混合纳米流体。这些被广泛表征,以确定是否传热过程的效率发生在这类植物可以提高。因此,分析了时间物理稳定性,纳米流体在几天后达到稳定状态,并保持了40多天。稳定后,对纳米流体感兴趣的特性进行测量,即密度、表面张力、动态粘度、等压比热和导热系数。纳米流体的密度、表面张力和动态粘度值相对于基础流体没有显著变化。等压比热提高了5%,导热系数提高了约6%。所有测量的性质被用来估计纳米流体在聚光太阳能发电厂中的应用价值。发现两种纳米流体的增强率约为19%,这表明它们是CSP-PTC工厂中用作传热流体的有希望的选择。
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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