Engineering metal–organic frameworks for advanced ceramic composites

IF 3.5 3区材料科学 Q1 MATERIALS SCIENCE, CERAMICS

Journal of the American Ceramic Society Pub Date : 2025-03-21 DOI:10.1111/jace.20509

Yuqing Zhang, Jinzhao Shi, Zhangming Fu, Qi Zheng, Lianjun Wang, Wan Jiang

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Abstract

The pursuit of enhanced engineering properties and multifunctionality in ceramic materials has long been a critical research focus, driven by the need to expand their applications across diverse industries. Metal–organic frameworks (MOFs), distinguished by their exceptional structural versatility, including ultrahigh specific surface areas, tunable porosity, and customizable compositions, have recently been enormously explored for improving the mechanical properties and multifunctionality of ceramic materials. This review highlights the advantages and recent advancements in leveraging MOFs architectures to engineer advanced ceramic materials. Specifically, the roles of MOFs as sacrificial templates/precursors for reinforcement phases and high-energy nanoceramic powders as well as functional components to realize multifaceted functionalities were examined. Furthermore, the review showcases cutting-edge applications of MOFs-integrated ceramic composites in emerging domains, such as electromagnetic wave (EMW) absorption, seawater desalination and filtration, and gas adsorption and separation. Finally, the challenges associated with integrating MOFs into ceramics are discussed, along with future research directions. This review aims to bridge the gap between MOFs innovation and ceramic engineering, offering a roadmap for the design and construction of structurally and functionally integrated advanced ceramic composites.

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用于高级陶瓷复合材料的工程金属有机框架

长期以来，追求陶瓷材料的增强工程性能和多功能性一直是一个关键的研究重点，这是由于需要扩大其在不同行业的应用。金属有机框架（mof）以其特殊的结构通用性而闻名，包括超高比表面积，可调孔隙率和可定制的成分，最近在改善陶瓷材料的机械性能和多功能方面进行了大量探索。本文重点介绍了利用mof结构来设计先进陶瓷材料的优点和最新进展。具体而言，mof作为增强相和高能纳米陶瓷粉末的牺牲模板/前体以及实现多方面功能的功能部件的作用进行了研究。此外，综述了mofs集成陶瓷复合材料在电磁波吸收、海水淡化与过滤、气体吸附与分离等新兴领域的前沿应用。最后，讨论了将MOFs集成到陶瓷中所面临的挑战，以及未来的研究方向。本文旨在弥合mof创新与陶瓷工程之间的差距，为结构和功能一体化的先进陶瓷复合材料的设计和建造提供路线图。

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来源期刊

Journal of the American Ceramic Society 工程技术-材料科学：硅酸盐

CiteScore

7.50

自引率

7.70%

发文量

590

审稿时长

2.1 months

期刊介绍： The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.