{"title":"One-Step Solvothermally Synthesized Ni Doped MoS2@SnS2 Nanocomposite as a High Performance Supercapacitor Electrode Material","authors":"Ravindra Kumar, Ashish Kumar Keshari, Susanta Sinha Roy, Geetika Patel, Vemoori Raju, Sourav Sain, Gurupada Maity","doi":"10.1002/cnma.202400584","DOIUrl":null,"url":null,"abstract":"<p>In the present study, a Ni doped bimetallic sulfide Ni-MoS<sub>2</sub>@SnS<sub>2</sub> flower-like nanocomposite is synthesized via a facile one-step solvothermal method. The Ni-MoS<sub>2</sub>@SnS<sub>2</sub> with the unique structure and composition demonstrates superior supercapacitor performance (a specific capacitance of approximate 1150, and 878 F cm<sup>−2</sup> at the current density of 0.5 mA cm<sup>−2</sup> and 5 mA cm<sup>−2</sup>, respectively) in comparison to sole SnS<sub>2</sub> (a specific capacitance of about 486, and 445 F cm<sup>−2</sup> at the same parameters). This remarkable enhancement in the electrochemical performance of Ni-MoS<sub>2</sub>@SnS<sub>2</sub> may be attributed to synergic effect of bimetallic sulfides with flower-like structure as fast electronic transport and minimal volume variation of the formation of nanocomposite. More precisely, it exhibits 57.53 Wh kg<sup>−1</sup>, 1500.78 W kg<sup>−1</sup> energy and power density at 0.5 mA cm<sup>−2</sup>, respectively, along with the better capacity retention of 85.2 % at 1 mA cm<sup>−2</sup> even after 5000 constructive charge-discharge cycles. It is viable approach for the development and design of novel type electrode materials featuring with flower -like structure is proposed to enhance the structural stability of supercapacitor.</p>","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 4","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemNanoMat","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202400584","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
In the present study, a Ni doped bimetallic sulfide Ni-MoS2@SnS2 flower-like nanocomposite is synthesized via a facile one-step solvothermal method. The Ni-MoS2@SnS2 with the unique structure and composition demonstrates superior supercapacitor performance (a specific capacitance of approximate 1150, and 878 F cm−2 at the current density of 0.5 mA cm−2 and 5 mA cm−2, respectively) in comparison to sole SnS2 (a specific capacitance of about 486, and 445 F cm−2 at the same parameters). This remarkable enhancement in the electrochemical performance of Ni-MoS2@SnS2 may be attributed to synergic effect of bimetallic sulfides with flower-like structure as fast electronic transport and minimal volume variation of the formation of nanocomposite. More precisely, it exhibits 57.53 Wh kg−1, 1500.78 W kg−1 energy and power density at 0.5 mA cm−2, respectively, along with the better capacity retention of 85.2 % at 1 mA cm−2 even after 5000 constructive charge-discharge cycles. It is viable approach for the development and design of novel type electrode materials featuring with flower -like structure is proposed to enhance the structural stability of supercapacitor.
在本研究中,通过简单的一步溶剂热法合成了一种Ni掺杂双金属硫化物Ni-MoS2@SnS2花状纳米复合材料。与单一的SnS2相比,具有独特结构和组成的Ni-MoS2@SnS2具有更好的超级电容器性能(在电流密度为0.5 mA cm−2和5 mA cm−2时,比电容分别约为1150和878 F cm−2)(在相同参数下,比电容约为486和445 F cm−2)。这种显著的电化学性能增强可能是由于具有花状结构的双金属硫化物作为快速电子输运的协同效应和纳米复合材料形成的最小体积变化。更准确地说,它在0.5 mA cm - 2下的能量和功率密度分别为57.53 Wh kg - 1和1500.78 W kg - 1,即使在5000次建设性充放电循环后,在1 mA cm - 2下的容量保持率也达到85.2%。为开发和设计具有花状结构的新型电极材料,提高超级电容器的结构稳定性提供了可行的途径。
ChemNanoMatEnergy-Energy Engineering and Power Technology
CiteScore
6.10
自引率
2.60%
发文量
236
期刊介绍:
ChemNanoMat is a new journal published in close cooperation with the teams of Angewandte Chemie and Advanced Materials, and is the new sister journal to Chemistry—An Asian Journal.