Rapid Formation of Coating on the Surface of Cubic Boron Nitride by Thermal Explosion Reaction

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
Dan Hui Han, Chong Peng, Bao Yan Liang, Guang Tong Zhou, Bin Hao Wang
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引用次数: 0

Abstract

Through thermal explosion reaction, a composite coating was formed on the surface of cubic boron nitride particles using Ti/carbon black/polytetrafluoroethylene/cubic boron nitride powders as raw materials. The results indicate that after the thermal explosion reaction, the coating on the surface of cubic boron nitride particles mainly comprised Ti, TiC, TiN, and TiB2 phases. When the cubic boron nitride content in the raw material was less than 50%, its surface was well coated. The coating had a relatively small structure composed of a large number of nanoscale particles. A reaction mechanism underlying the thermal explosion-induced surface coating of cubic boron nitride had been proposed.

热爆炸反应在立方氮化硼表面快速形成涂层
通过热爆反应,以Ti/炭黑/聚四氟乙烯/立方氮化硼粉末为原料,在立方氮化硼颗粒表面形成复合涂层。结果表明:热爆炸反应后,立方氮化硼颗粒表面的涂层主要由Ti、TiC、TiN和TiB2相组成;当原料中立方氮化硼含量小于50%时,其表面包覆良好。该涂层具有由大量纳米级粒子组成的相对较小的结构。提出了热爆致立方氮化硼表面涂层的反应机理。
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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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