Toward design of novel materials for lithium-ion batteries: Aluminium nanoparticle-assisted seaweed-based separator

Abstract

Separators are a crucial component and play a pivotal role in battery performance and safety. In this study, a cellulose nanofibril separator was prepared from red algae. The generated nanosized cellulose fibrils were used in the preparation of the separator. The produced separator was analyzed for electrochemical performance, thermal stability, and morphology in comparison to the commercial polyethylene (PE) separator. The obtained densely linked nanoporous separator exhibited a capacity retention of 80% over 600 cycles. It had very good wettability and ionic conductivity results due to its excellent hydrophilic nature enhanced by the presence of the hydroxyl groups. The excellent physical properties of the aluminium nanoparticle-assisted seaweed-based separator (ASS) due to the presence of Al₂O₃, aided in its resilience to heat and maintained its dimensions. It exhibited greater electrochemical performance compared to the commercial PE. At 2C the discharge specific capacity was at 83 mAh/g for ASS and PE 77 mAh/g. However, the separators both exhibited comparable results at low C-rates. This study offers an achievable option for the production of an effective seaweed-based separator for use in lithium-ion batteries exceptional physical properties.