{"title":"General matrix method for critical investigation of physical properties of biodiesels: A comprehensive study","authors":"Narayan Gaonkar, R.G. Vaidya","doi":"10.1016/j.molliq.2025.127568","DOIUrl":null,"url":null,"abstract":"<div><div>General matrix method is developed for the understanding of properties of biodiesel blends. This paper presents systematic investigations and overview of state-of-the-art methods for the analysis of density (<span><math><mrow><mi>ρ</mi></mrow></math></span>) and viscosity (<span><math><mrow><mi>μ</mi></mrow></math></span>) and comprehensive study of <span><math><mrow><mi>ρ</mi></mrow></math></span> and <span><math><mrow><mi>μ</mi></mrow></math></span> of biodiesel blends using matrix method for the available reports. The critical investigations on key issues of existing empirical relations and models are discussed. Investigations focus distinctly on the relevant aspects of generalization of matrix method over the contemporary studies and perspectives reported in the literature. Matrix method is found to be one of the most general methods with which the empirical relations for <span><math><mrow><mi>ρ</mi></mrow></math></span> and <span><math><mrow><mi>μ</mi></mrow></math></span> for any biodiesel blends can be generated. For the first time, the critical analysis and direct comparison of unique correlation constants for each biodiesel blends connecting to rate of variation of properties of biodiesel blends with temperature and volume percent are presented. The degree of accuracy of the method is highlighted in view of past decade experimental and modelling reports. The matrix method is advantageous over existing correlations with its simplicity, direct comparison possibilities and general applicability to all biodiesel blends. Our study gives new fundamental insights for physical properties of biodiesel blends and provides practical road map for biodiesel blends applications.</div></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":"428 ","pages":"Article 127568"},"PeriodicalIF":5.3000,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Liquids","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167732225007354","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
General matrix method is developed for the understanding of properties of biodiesel blends. This paper presents systematic investigations and overview of state-of-the-art methods for the analysis of density () and viscosity () and comprehensive study of and of biodiesel blends using matrix method for the available reports. The critical investigations on key issues of existing empirical relations and models are discussed. Investigations focus distinctly on the relevant aspects of generalization of matrix method over the contemporary studies and perspectives reported in the literature. Matrix method is found to be one of the most general methods with which the empirical relations for and for any biodiesel blends can be generated. For the first time, the critical analysis and direct comparison of unique correlation constants for each biodiesel blends connecting to rate of variation of properties of biodiesel blends with temperature and volume percent are presented. The degree of accuracy of the method is highlighted in view of past decade experimental and modelling reports. The matrix method is advantageous over existing correlations with its simplicity, direct comparison possibilities and general applicability to all biodiesel blends. Our study gives new fundamental insights for physical properties of biodiesel blends and provides practical road map for biodiesel blends applications.
期刊介绍:
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
– Colloidal solutions and nanoparticles
– Thermotropic and lyotropic liquid crystals
– Ferrofluids
– Water, aqueous solutions and other hydrogen-bonded liquids
– Lubricants, polymer solutions and melts
– Molten metals and salts
– Phase transitions and critical phenomena in liquids and confined fluids
– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
– Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.)
– Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.)
– Light scattering (Rayleigh, Brillouin, PCS, etc.)
– Dielectric relaxation
– X-ray and neutron scattering and diffraction.
Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.