General matrix method for critical investigation of physical properties of biodiesels: A comprehensive study

IF 5.3 2区 化学 Q2 CHEMISTRY, PHYSICAL
Narayan Gaonkar, R.G. Vaidya
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引用次数: 0

Abstract

General matrix method is developed for the understanding of properties of biodiesel blends. This paper presents systematic investigations and overview of state-of-the-art methods for the analysis of density (ρ) and viscosity (μ) and comprehensive study of ρ and μ of biodiesel blends using matrix method for the available reports. The critical investigations on key issues of existing empirical relations and models are discussed. Investigations focus distinctly on the relevant aspects of generalization of matrix method over the contemporary studies and perspectives reported in the literature. Matrix method is found to be one of the most general methods with which the empirical relations for ρ and μ for any biodiesel blends can be generated. For the first time, the critical analysis and direct comparison of unique correlation constants for each biodiesel blends connecting to rate of variation of properties of biodiesel blends with temperature and volume percent are presented. The degree of accuracy of the method is highlighted in view of past decade experimental and modelling reports. The matrix method is advantageous over existing correlations with its simplicity, direct comparison possibilities and general applicability to all biodiesel blends. Our study gives new fundamental insights for physical properties of biodiesel blends and provides practical road map for biodiesel blends applications.
生物柴油物理性质关键研究的一般矩阵法:综合研究
为了解生物柴油混合物的性质,开发了通用矩阵法。本文系统地介绍了密度(ρ)和粘度(μ)分析的最新方法,并利用矩阵法对生物柴油混合物的ρ和μ进行了综合研究。讨论了对现有经验关系和模型的关键问题的批判性研究。与文献中报道的当代研究和观点相比,调查明显侧重于矩阵方法泛化的相关方面。矩阵法是最通用的方法之一,它可以生成任何生物柴油混合物的ρ和μ的经验关系。本文首次对每一种生物柴油混合物的特性随温度和体积百分比的变化率的独特相关常数进行了批判性分析和直接比较。根据过去十年的实验和建模报告,强调了该方法的准确性。矩阵法的优势在于其简单、直接比较的可能性和对所有生物柴油混合物的普遍适用性。我们的研究为生物柴油混合物的物理性质提供了新的基本见解,并为生物柴油混合物的应用提供了实用的路线图。
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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