Investigating the Photoregrouping of Thioester Esters Based on Effects from the Chemical Polarization of Nuclei

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2025-04-05 DOI:10.1134/S0036024424703370

V. I. Porkhun, N. A. Kuznetsova, A. G. Podoprigora, Yu. V. Bogdanova

引用次数: 0

Abstract

Fries’ photo-rearrangement of the thioester of para-methyl benzocarbothiol in a number of solvents is studied by means of CIDNP. It is shown that the reaction proceeds with the formation of radical pairs in the singlet state. Elementary stages of the reaction are determined.

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基于原子核化学极化效应的硫酯酯光重组研究

利用CIDNP研究了对甲基苯并碳硫醇硫酯在多种溶剂中的Fries光重排。结果表明，该反应是在单线态下形成自由基对的。反应的基本阶段确定了。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.