{"title":"On the Escape of a Diffusing Particle from a Cavity","authors":"V. Yu. Zitserman, Yu. A. Makhnovskii","doi":"10.1134/S0036024424703308","DOIUrl":null,"url":null,"abstract":"<p>The problem about an exit of a Brownian particle from a cylindrical cavity through an opening on the surface of one of the cylinder ends is considered. A one-dimensional description of the process using the surface homogenization method is proposed. The solution obtained by this method allows us to find the average lifetime of a particle in such a cavity with any hole size. The qualitative difference from the well-known solution for the average lifetime of a particle diffusing in an isometric (sphere-like) cavity lies in the fact that the previously obtained result depends only on the cavity volume, while the solution found in this work depends not only on the cylinder volume, but also on its length.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 2","pages":"279 - 282"},"PeriodicalIF":0.7000,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424703308","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The problem about an exit of a Brownian particle from a cylindrical cavity through an opening on the surface of one of the cylinder ends is considered. A one-dimensional description of the process using the surface homogenization method is proposed. The solution obtained by this method allows us to find the average lifetime of a particle in such a cavity with any hole size. The qualitative difference from the well-known solution for the average lifetime of a particle diffusing in an isometric (sphere-like) cavity lies in the fact that the previously obtained result depends only on the cavity volume, while the solution found in this work depends not only on the cylinder volume, but also on its length.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.