{"title":"Groundwater of the Eastern Egyptian Desert: age and salinity patterns","authors":"Manal Wannous , Christian Siebert","doi":"10.1016/j.apgeochem.2025.106367","DOIUrl":null,"url":null,"abstract":"<div><div>The increasing development of groundwater dependent irrigation projects and desalination activities along the Red Sea coast raises questions about its recharge mechanisms and the geochemical processes driving salinity variations. To address these questions, several wells and springs, along the Red Sea Hills have been sampled and analysed for radiocarbon, tritium, δ<sup>13</sup>C, δ<sup>18</sup>O, δ<sup>2</sup>H and their chemistry. For the same period between 2019-2021, rain and floodwater samples have been collected from sporadic rain events in the region. The sampling locations are geographically clustered and classified into six distinct groundwater types based on geochemical composition and isotopic signatures. The distinguished types exhibits a diverse range of geochemical and isotopic characteristics, reflecting variable flow paths, recharge periods, and lithological interactions. Freshwater springs in Wadi Araba are characterized by minimal salinization and light stable isotopes, suggesting Pleistocene recharge. These springs, emerge from fractures and are influenced by the weathering of Na-bearing minerals in the underlying Nubian Sandstone. In contrast, groundwater from the coastal plain shows significant contributions from seawater evaporation brines, with isotopic signatures following an evaporation trend. These waters vary widely in age, from recent to Pleistocene, indicating similar lithological interactions despite differing flow paths. Another group of groundwater is influenced primarily by the weathering of halite, gypsum, and dolostone, showing no significant brine contribution. Highly saline groundwater are rare and stands out with extreme brine contributions likely sourced from deep crustal formations. Groundwater with elevated Na/Cl ratios, found in regions of Wadi Araba and the Red Sea Hills, reflects the weathering of Na-bearing minerals such as feldspars in magmatic rocks or clastic sandstones. These waters contrast sharply with those influenced by seawater or evaporation brines, highlighting the complex interplay of lithology, recharge processes, and tectonic activity in shaping the region’s groundwater systems.</div></div>","PeriodicalId":8064,"journal":{"name":"Applied Geochemistry","volume":"184 ","pages":"Article 106367"},"PeriodicalIF":3.1000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Geochemistry","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0883292725000903","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
Abstract
The increasing development of groundwater dependent irrigation projects and desalination activities along the Red Sea coast raises questions about its recharge mechanisms and the geochemical processes driving salinity variations. To address these questions, several wells and springs, along the Red Sea Hills have been sampled and analysed for radiocarbon, tritium, δ13C, δ18O, δ2H and their chemistry. For the same period between 2019-2021, rain and floodwater samples have been collected from sporadic rain events in the region. The sampling locations are geographically clustered and classified into six distinct groundwater types based on geochemical composition and isotopic signatures. The distinguished types exhibits a diverse range of geochemical and isotopic characteristics, reflecting variable flow paths, recharge periods, and lithological interactions. Freshwater springs in Wadi Araba are characterized by minimal salinization and light stable isotopes, suggesting Pleistocene recharge. These springs, emerge from fractures and are influenced by the weathering of Na-bearing minerals in the underlying Nubian Sandstone. In contrast, groundwater from the coastal plain shows significant contributions from seawater evaporation brines, with isotopic signatures following an evaporation trend. These waters vary widely in age, from recent to Pleistocene, indicating similar lithological interactions despite differing flow paths. Another group of groundwater is influenced primarily by the weathering of halite, gypsum, and dolostone, showing no significant brine contribution. Highly saline groundwater are rare and stands out with extreme brine contributions likely sourced from deep crustal formations. Groundwater with elevated Na/Cl ratios, found in regions of Wadi Araba and the Red Sea Hills, reflects the weathering of Na-bearing minerals such as feldspars in magmatic rocks or clastic sandstones. These waters contrast sharply with those influenced by seawater or evaporation brines, highlighting the complex interplay of lithology, recharge processes, and tectonic activity in shaping the region’s groundwater systems.
期刊介绍:
Applied Geochemistry is an international journal devoted to publication of original research papers, rapid research communications and selected review papers in geochemistry and urban geochemistry which have some practical application to an aspect of human endeavour, such as the preservation of the environment, health, waste disposal and the search for resources. Papers on applications of inorganic, organic and isotope geochemistry and geochemical processes are therefore welcome provided they meet the main criterion. Spatial and temporal monitoring case studies are only of interest to our international readership if they present new ideas of broad application.
Topics covered include: (1) Environmental geochemistry (including natural and anthropogenic aspects, and protection and remediation strategies); (2) Hydrogeochemistry (surface and groundwater); (3) Medical (urban) geochemistry; (4) The search for energy resources (in particular unconventional oil and gas or emerging metal resources); (5) Energy exploitation (in particular geothermal energy and CCS); (6) Upgrading of energy and mineral resources where there is a direct geochemical application; and (7) Waste disposal, including nuclear waste disposal.