(5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine)platinum(II) dinitrate methanol disolvate

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2025-04-01 DOI:10.1107/S2056989025001847

Ashley Jurisinec , Yingjie Zhang , Janice R. Aldrich-Wright

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引用次数: 0

Abstract

The title platinum(II) complex exhibits a distorted square-planar geometry. Intra- and intermolecular π-stacking interactions are observed between the phenanthroline and phosphine rings while hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.

The title compound, [Pt(C₁₄H₁₂N₂)(C₂₁H₂₁N₂P)](NO₃)₂·2CH₃OH, is a platinum(II) complex, which crystallizes in a monoclinic (P2₁/c) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine ligand. The structure reveals both intra- and intermolecular π-stacking interactions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.

(5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(di­phenyl­phosphan­yl)benzyl­idene]amino}­ethan-1-amine)­platinum(II) dinitrate methanol disolvate

Abstract

(5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine)platinum(II) dinitrate methanol disolvate