Joel Gichumbi , Holger B. Friedrich , Sizwe J. Zamisa
{"title":"Chlorido{2-[(4-chlorophenyl)iminomethyl]pyridine-κ2N,N′}(η6-toluene)ruthenium(II) hexafluoridophosphate","authors":"Joel Gichumbi , Holger B. Friedrich , Sizwe J. Zamisa","doi":"10.1107/S2414314625001038","DOIUrl":null,"url":null,"abstract":"<div><div>The crystal structure of an arene ruthenium(II) complex bearing a bidentate Schiff base ligand is reported.</div></div><div><div>The asymmetric unit of the title compound, [RuCl(C<sub>7</sub>H<sub>8</sub>)(C<sub>12</sub>H<sub>9</sub>ClN<sub>2</sub>)]PF<sub>6</sub>, contains two cationic ruthenium(II) complexes and two [PF<sub>6</sub>]<sup>−</sup> anions. One of the anions exhibits disorder over two positions. The ruthenium complex adopts a piano-stool geometry, with chelating Schiff base and chlorido ligands occupying three coordination sites, and the arene ring serving as the ‘seat’.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (278KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314625000227","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The crystal structure of an arene ruthenium(II) complex bearing a bidentate Schiff base ligand is reported.
The asymmetric unit of the title compound, [RuCl(C7H8)(C12H9ClN2)]PF6, contains two cationic ruthenium(II) complexes and two [PF6]− anions. One of the anions exhibits disorder over two positions. The ruthenium complex adopts a piano-stool geometry, with chelating Schiff base and chlorido ligands occupying three coordination sites, and the arene ring serving as the ‘seat’.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
