Fabrication and characterization of electrically conducting electrospun mediator-less polyaniline-based enzymatic biofuel cell anode

IF 4.3 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Chemistry and Physics Pub Date : 2025-03-25 DOI:10.1016/j.matchemphys.2025.130814

Ifra Khanam, Inamuddin

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引用次数: 0

Abstract

A bioanode of polyaniline (PANI) and polystyrene modified with redox enzyme glucose oxidase was fabricated by using electrospinning. The bioanode was prepared by depositing the electrospun fibers over a glassy carbon electrode (GCE). The bioanode composite was characterized by FTIR (Fourier transform infrared spectroscopy), TGA (Thermogravimetric analysis), XRD (X-ray diffraction), SEM (Scanning electron microscopy), and HR-SEM (High resonance scanning electron microscopy). The electrochemical characteristics of the fibrous anode are studied by cyclic voltammetry (CV), linear sweep voltammetry (LSV), and electrochemical impedance spectroscopy (EIS). The maximum current density provided by the GCE/PANI-polystyrene/GOx nanofibers was 2.689 mA cm⁻² in the presence of 20 mM glucose, indicating the successful glucose-sensing ability of the GOx-modified anode. The mentioned bioanode showed significant operational stability. Fabricating fibrous matrix opens a gateway to explore its possible exploitation in wearable and miniatured EBFCs for future research.

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来源期刊

Materials Chemistry and Physics 工程技术-材料科学：综合

CiteScore

8.70

自引率

4.30%

发文量

1515

审稿时长

69 days

期刊介绍： Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.