M. M. Prokopiv, O. V. Kharchenko, Yu. P. Uschapovskyi, I. V. Lisovska, I. M. Zakiev
{"title":"Hard WС–(Ті,W)C–10Со Alloy with Increased Hardness and Strength","authors":"M. M. Prokopiv, O. V. Kharchenko, Yu. P. Uschapovskyi, I. V. Lisovska, I. M. Zakiev","doi":"10.3103/S1063457625010083","DOIUrl":null,"url":null,"abstract":"<p>Some characteristics are reported for modified hard alloy T5K10 formed under the conditions of purposeful control over the thermokinetic free vacuum sintering parameters minimizing the processes of solid- and liquid-phase interaction between tungsten carbide and cobalt, which determine the redistribution and recrystallization of carbide grains. The synthesized WС–(Ті,W)C–10Со hard alloy is characterized by a homogeneous finely grained structure, a high density (ρ = 12.98 g/cm<sup>3</sup>), a low level of residual microporosity, a bimodal composition of WC grains, and bridges between carbide grains. As compared to the commercial analogue, the synthesized hard alloy has a 2.4 GPa higher hardness (<i>Н</i><sub>V</sub> = 15), a 270 MPa higher mechanical bending strength, a 1.4 MPa m<sup>0.5</sup> higher fracture toughness, and 1.5 times higher wear resistance. The modification of sintering technology and structural transformations in the synthesized WС–(Ті,W)C–10Со hard alloy have result in a 2.5-fold increase in its service durability during rough steel turning (forged axles of a railway wagons platform) and, in the case of deep soil chiseling, an increase in abrasion resistance is 48%.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"47 1","pages":"20 - 29"},"PeriodicalIF":1.2000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Superhard Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.3103/S1063457625010083","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Some characteristics are reported for modified hard alloy T5K10 formed under the conditions of purposeful control over the thermokinetic free vacuum sintering parameters minimizing the processes of solid- and liquid-phase interaction between tungsten carbide and cobalt, which determine the redistribution and recrystallization of carbide grains. The synthesized WС–(Ті,W)C–10Со hard alloy is characterized by a homogeneous finely grained structure, a high density (ρ = 12.98 g/cm3), a low level of residual microporosity, a bimodal composition of WC grains, and bridges between carbide grains. As compared to the commercial analogue, the synthesized hard alloy has a 2.4 GPa higher hardness (НV = 15), a 270 MPa higher mechanical bending strength, a 1.4 MPa m0.5 higher fracture toughness, and 1.5 times higher wear resistance. The modification of sintering technology and structural transformations in the synthesized WС–(Ті,W)C–10Со hard alloy have result in a 2.5-fold increase in its service durability during rough steel turning (forged axles of a railway wagons platform) and, in the case of deep soil chiseling, an increase in abrasion resistance is 48%.
期刊介绍:
Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.