{"title":"A comparative study of Ku-band absorption characteristics and analysis of structural properties of Ba1-xGdxFe12O19 (0.00≤x≤0.50) samples","authors":"Garima Sharda , Pawandeep Kaur , Sandeep Sharma , Anupinder Singh , Paramjeet Kaur , Sachin Kumar Godara , Jahangeer Ahmed , Saad M. Alshehri , Abhishek Kandwal , Mandeep Singh","doi":"10.1016/j.matchemphys.2025.130771","DOIUrl":null,"url":null,"abstract":"<div><div>The solid state method was utilized to prepare Ba<sub>1-x</sub>Gd<sub>x</sub>Fe<sub>12</sub>O<sub>19</sub> (0.00 ≤ x ≤ 0.50) samples. The XRD (profile matching) data indicated the presence of additional impurity (Fe<sub>2</sub>O<sub>3</sub> and Gd<sub>3</sub>Fe<sub>2</sub>Fe<sub>3</sub>O<sub>12</sub>) phases besides the M-type Ba<sub>1-x</sub>Gd<sub>x</sub>Fe<sub>12</sub>O<sub>19</sub> phase for x > 0.10. The concentration of M-type phase decreased from 100 % (at x = 0.00) to 40.69 % (at x = 0.50). The XRD data hence shows the multiphase nature of these samples. FESEM data established average grain size ≈0.75 μm in x = 0.20 and 0.40 samples. VNA data shows that ε′ and μ′ spectra are complementary to each other. Highest K<sub>u</sub>-band response (<span><math><mrow><mi>R</mi><mi>L</mi><mrow><mo>(</mo><mrow><mi>d</mi><mi>B</mi></mrow><mo>)</mo></mrow></mrow></math></span>) has been observed for the x = 0.1 sample. For this sample a <span><math><mrow><mi>R</mi><mi>L</mi><mrow><mo>(</mo><mrow><mi>d</mi><mi>B</mi></mrow><mo>)</mo></mrow></mrow></math></span> value <strong>≈</strong> −18.12 dB has been observed at 12.40 GHz. The x = 0.5 sample exhibits insufficient microwave response (<span><math><mrow><mi>R</mi><mi>L</mi><mo>(</mo><mrow><mi>d</mi><mi>B</mi></mrow></mrow></math></span> = - 9.79 > −10 dB). Highest bandwidth (≈4.43 GHz) has been observed for x = 0.30 sample. The <span><math><mrow><mi>R</mi><mi>L</mi><mrow><mo>(</mo><mrow><mi>d</mi><mi>B</mi></mrow><mo>)</mo></mrow></mrow></math></span> data suggests effective microwave response for x ≤ 0.40 samples. Further, the <span><math><mrow><mi>R</mi><mi>L</mi><mrow><mo>(</mo><mrow><mi>d</mi><mi>B</mi></mrow><mo>)</mo></mrow></mrow></math></span> data corroborates nicely with the impedance matching data. The varying values of C<sub>0</sub> parameter with frequency suggest that natural resonance is responsible for magnetic losses in these samples. The total shielding effectiveness of various samples varies between 16.90 dB (for x = 0.50) and – 19.44 dB (for x = 0.00).</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"339 ","pages":"Article 130771"},"PeriodicalIF":4.3000,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Chemistry and Physics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0254058425004171","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The solid state method was utilized to prepare Ba1-xGdxFe12O19 (0.00 ≤ x ≤ 0.50) samples. The XRD (profile matching) data indicated the presence of additional impurity (Fe2O3 and Gd3Fe2Fe3O12) phases besides the M-type Ba1-xGdxFe12O19 phase for x > 0.10. The concentration of M-type phase decreased from 100 % (at x = 0.00) to 40.69 % (at x = 0.50). The XRD data hence shows the multiphase nature of these samples. FESEM data established average grain size ≈0.75 μm in x = 0.20 and 0.40 samples. VNA data shows that ε′ and μ′ spectra are complementary to each other. Highest Ku-band response () has been observed for the x = 0.1 sample. For this sample a value ≈ −18.12 dB has been observed at 12.40 GHz. The x = 0.5 sample exhibits insufficient microwave response ( = - 9.79 > −10 dB). Highest bandwidth (≈4.43 GHz) has been observed for x = 0.30 sample. The data suggests effective microwave response for x ≤ 0.40 samples. Further, the data corroborates nicely with the impedance matching data. The varying values of C0 parameter with frequency suggest that natural resonance is responsible for magnetic losses in these samples. The total shielding effectiveness of various samples varies between 16.90 dB (for x = 0.50) and – 19.44 dB (for x = 0.00).
期刊介绍:
Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.