Thermodynamics and crystallography of hard light-element boron-rich compounds by in situ X-ray diffraction under high-pressure, high-temperature conditions

IF 3.4 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Solid State Sciences Pub Date : 2025-03-21 DOI:10.1016/j.solidstatesciences.2025.107909

Alexandre Courac , Vladimir Turkevich , Yann Le Godec

引用次数: 0

Abstract

Here we review the available experimental and theoretical data on phase transformations and thermodynamical properties of boron compounds that can be obtained by in situ methods at high-pressure and high-temperature (HPHT) conditions. The thermodynamic analysis allowed to establish the optimized sets of thermodynamic values and mechanical properties for boron allotropes and compounds such as boron suboxide B₆O, boron subnitride B₁₃N₂, and boron carbide.

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在高压、高温条件下用原位x射线衍射研究富硼硬轻元素化合物的热力学和晶体学

本文综述了在高压和高温条件下原位法获得的硼化合物相变和热力学性质的实验和理论数据。热力学分析允许建立优化的硼同素异形体和化合物（如亚氧化硼b60、亚氮化硼B13N2和碳化硼）的热力学值和力学性能集。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Solid State Sciences 化学-无机化学与核化学

CiteScore

6.60

自引率

2.90%

发文量

214

审稿时长

27 days

期刊介绍： Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments. Key topics for stand-alone papers and special issues: -Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials -Physical properties, emphasizing but not limited to the electrical, magnetical and optical features -Materials related to information technology and energy and environmental sciences. The journal publishes feature articles from experts in the field upon invitation. Solid State Sciences - your gateway to energy-related materials.