Yilin Meng , Chunming Wang , Wei Zhang , Hailei Meng , Hao Shen , Jun Yong , Chao Zhou , Hui Liu
{"title":"Surface renewal mechanism during laser-cleaning of aged silicone rubber composites","authors":"Yilin Meng , Chunming Wang , Wei Zhang , Hailei Meng , Hao Shen , Jun Yong , Chao Zhou , Hui Liu","doi":"10.1016/j.matchemphys.2025.130728","DOIUrl":null,"url":null,"abstract":"<div><div>Silicone rubber composite insulators are an important component of the power grid, but prolonged use can cause surface aging and decrease hydrophobicity, leading to safety hazards. Removing aged silicone rubber can improve hydrophobicity and extend service time, but there is no suitable means to achieve these objectives due to the high safety requirements of transmission lines. Therefore, we researched laser cleaning technology to remove aged silicone rubber to restore hydrophobicity. The effect of removal depth and microscopic morphology under defocusing and spot overlap were investigated. It was found that silicone rubber was mainly removed by decomposition when the defocusing was less than 20 mm, while combustion removal occurred when the defocusing was more than 30 mm. The spherical, massive and irregular particles were produced by the decomposition mechanism, while products with porous structure were generated by combustion. Both decomposition and combustion could effectively improve the hydrophobicity of aged composite insulators. The maximum contact angle could be increased from 75° to about 140°, but combustion increased the surface roughness from Ra 1.78 μm to a maximum of Ra 6 μm, while the maximum roughness is only Ra 3 μm with decomposition. The Shore A hardness of the laser-treated samples remained relatively stable, ranging from 76 HA to 80 HA.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"339 ","pages":"Article 130728"},"PeriodicalIF":4.3000,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Chemistry and Physics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0254058425003748","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Silicone rubber composite insulators are an important component of the power grid, but prolonged use can cause surface aging and decrease hydrophobicity, leading to safety hazards. Removing aged silicone rubber can improve hydrophobicity and extend service time, but there is no suitable means to achieve these objectives due to the high safety requirements of transmission lines. Therefore, we researched laser cleaning technology to remove aged silicone rubber to restore hydrophobicity. The effect of removal depth and microscopic morphology under defocusing and spot overlap were investigated. It was found that silicone rubber was mainly removed by decomposition when the defocusing was less than 20 mm, while combustion removal occurred when the defocusing was more than 30 mm. The spherical, massive and irregular particles were produced by the decomposition mechanism, while products with porous structure were generated by combustion. Both decomposition and combustion could effectively improve the hydrophobicity of aged composite insulators. The maximum contact angle could be increased from 75° to about 140°, but combustion increased the surface roughness from Ra 1.78 μm to a maximum of Ra 6 μm, while the maximum roughness is only Ra 3 μm with decomposition. The Shore A hardness of the laser-treated samples remained relatively stable, ranging from 76 HA to 80 HA.
期刊介绍:
Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.