{"title":"Sodium Hexa-titanate nanocomposites modified with trace amounts of ruthenium displayed enhanced supercapacitance","authors":"Akansha Seervi , Jesse S. Dondapati , Akhtar Bayat , Seshasai Srinivasan , Amin Reza Rajabzadeh","doi":"10.1016/j.matchemphys.2025.130776","DOIUrl":null,"url":null,"abstract":"<div><div>Sodium hexa-titanate (Na<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub>) nanostructures exhibit high electrochemical surface area and unique structural properties. In this study, sodium hexa-titanate nanostructures were grown from titanium (Ti) substrate (Ti/Na<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub>) and were investigated for supercapacitance by doping oxygen vacancies and modifying with trace amounts of ruthenium (Ru) to form nanostructure composites. An electrochemical reduction method was used for inducing oxygen vacancies into the lattice structure of Ti/Na<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub> nanocomposites to enhance electrochemical and supercapacitance properties. Several Characterization techniques like EDS, XRD and XPS were employed to identify and optimize structure property relationship to achieve supercapacitance. An enhanced specific capacitance of 3300 mF cm<sup>−2</sup>g<sup>−1</sup> was achieved for Ru–Ti/Na<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub> for Ru ultra-low loading of 0.4 μg of Ru in contrast to a specific capacitance of 100 mF cm<sup>−2</sup>g<sup>−1</sup> observed for unmodified Ti/Na<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub>.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"339 ","pages":"Article 130776"},"PeriodicalIF":4.3000,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Chemistry and Physics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0254058425004225","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Sodium hexa-titanate (Na2Ti6O13) nanostructures exhibit high electrochemical surface area and unique structural properties. In this study, sodium hexa-titanate nanostructures were grown from titanium (Ti) substrate (Ti/Na2Ti6O13) and were investigated for supercapacitance by doping oxygen vacancies and modifying with trace amounts of ruthenium (Ru) to form nanostructure composites. An electrochemical reduction method was used for inducing oxygen vacancies into the lattice structure of Ti/Na2Ti6O13 nanocomposites to enhance electrochemical and supercapacitance properties. Several Characterization techniques like EDS, XRD and XPS were employed to identify and optimize structure property relationship to achieve supercapacitance. An enhanced specific capacitance of 3300 mF cm−2g−1 was achieved for Ru–Ti/Na2Ti6O13 for Ru ultra-low loading of 0.4 μg of Ru in contrast to a specific capacitance of 100 mF cm−2g−1 observed for unmodified Ti/Na2Ti6O13.
期刊介绍:
Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.