DDT run-up distance for stoichiometric hydrogen-methane-oxygen measured in an orifice plate filled tube

IF 5.8 2区 工程技术 Q2 ENERGY & FUELS
Chuanyu Pan , Xishi Wang , Gaby Ciccarelli
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引用次数: 0

Abstract

Flame acceleration and deflagration-to-detonation transition (DDT) was studied in a 2.88-m, 7.6-cm inner-diameter transparent round tube filled with repeating 50 % blockage-ratio orifice plates. Stoichiometric hydrogen/methane/oxygen, with different hydrogen-to-methane mole ratios, and argon-diluted stoichiometric hydrogen-oxygen mixtures were tested. These mixtures span a range of detonation cell structure regularity. The reactivity of the mixture was controlled by varying the initial pressure, from the DDT critical pressure to a maximum of 40 kPa. Flame velocity was measured from high-speed video. The DDT run-up distance was obtained directly from the video images, and soot foils were used to confirm the DDT location at the critical initial pressure and to measure the detonation cell size at the end of the tube void of obstacles. The DDT run-up distance was shorter for methane containing mixtures at the lowest initial pressure near the DDT limit but was the same for all mixtures at pressures greater than 15 kPa. For each mixture, the DDT run-up distance decreased with the detonation cell size according to an inverse power-law. For a given detonation cell size, the DDT run-up distance decreases with increased methane-fraction. Therefore, for a given orifice diameter, at the DDT limit (where the orifice diameter roughly equals the detonation cell size), the DDT run-up distance for methane-containing mixtures is shorter than for 100 % hydrogen. This, and the fact that a higher initial pressure is required for methane containing mixtures to have the same cell size, needs to be considered when assessing the explosion hazard of hydrogen/methane mixtures.
在孔板填充管中测定化学计量氢-甲烷-氧的滴滴涕助燃距离
在一个直径2.88 m,内径7.6 cm的透明圆管内,用重复50%堵塞率的孔板填充火焰加速和爆燃-爆轰过渡(DDT)。测试了不同氢/甲烷摩尔比下的化学计量氢/甲烷/氧,以及氩气稀释的化学计量氢-氧混合物。这些混合物跨越了爆轰室结构的规律性范围。混合物的反应性是通过改变初始压力来控制的,从滴滴涕临界压力到最大40千帕。火焰速度通过高速视频测量。直接从视频图像中获得滴滴涕的起飞距离,并利用烟灰箔确定滴滴涕在临界初始压力下的位置,并测量障碍物管腔末端的爆轰池尺寸。在接近滴滴涕极限的最低初始压力下,含甲烷混合物的滴滴涕上升距离较短,但在压力大于15千帕时,所有混合物的滴滴涕上升距离都相同。对于每种混合物,滴滴涕助燃距离随爆轰池尺寸呈反比幂律减小。对于给定爆轰池尺寸,滴滴涕助燃距离随甲烷组分的增加而减小。因此,对于给定的孔直径,在滴滴涕极限(孔直径大致等于爆轰池尺寸)下,含甲烷混合物的滴滴涕上升距离比100%氢的混合物短。在评估氢气/甲烷混合物的爆炸危险性时,需要考虑到这一点,以及含有甲烷的混合物需要更高的初始压力才能具有相同的容器尺寸。
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来源期刊
Combustion and Flame
Combustion and Flame 工程技术-工程:化工
CiteScore
9.50
自引率
20.50%
发文量
631
审稿时长
3.8 months
期刊介绍: The mission of the journal is to publish high quality work from experimental, theoretical, and computational investigations on the fundamentals of combustion phenomena and closely allied matters. While submissions in all pertinent areas are welcomed, past and recent focus of the journal has been on: Development and validation of reaction kinetics, reduction of reaction mechanisms and modeling of combustion systems, including: Conventional, alternative and surrogate fuels; Pollutants; Particulate and aerosol formation and abatement; Heterogeneous processes. Experimental, theoretical, and computational studies of laminar and turbulent combustion phenomena, including: Premixed and non-premixed flames; Ignition and extinction phenomena; Flame propagation; Flame structure; Instabilities and swirl; Flame spread; Multi-phase reactants. Advances in diagnostic and computational methods in combustion, including: Measurement and simulation of scalar and vector properties; Novel techniques; State-of-the art applications. Fundamental investigations of combustion technologies and systems, including: Internal combustion engines; Gas turbines; Small- and large-scale stationary combustion and power generation; Catalytic combustion; Combustion synthesis; Combustion under extreme conditions; New concepts.
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