Sources and health risk of metallic elements assessment: a study of a representative industrial city.

IF 3.2 3区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL
Jinfeng Xiao, Yongchao Sun, Jianjiang Lu, Li Cao, Zilong Liu, Yujun Yan, Weijun Li, Shaohua He
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Abstract

PM2.5 in the air can adsorb a wide range of substances, and due to their small size, they can carry toxic and hazardous substances into the human body through inhalation, which can be harmful to human health. PM2.5 samples were collected in Shihezi for one year from September 2021 to August 2022 to characterise the distribution of 13 metallic elements in PM2.5 and their potential sources. The findings revealed that the concentrations of PM2.5 surpassed the national threshold of 35 μg/m3, alongside elevated levels of crustal elements. To assess the potential sources of the 13 metallic elements, present in PM2.5, a comprehensive analysis was conducted utilizing Enrichment Factor analysis, principal component analysis (PCA), and Backward Trajectory Modelling. The Enrichment Factors analysis revealed that five elements were significantly influenced by anthropogenic activities, with cadmium exhibiting particularly high levels of enrichment. PCA indicated that the metal elements were predominantly sourced from coal combustion, vehicular emissions, dust, fossil fuel combustion and industrial activities. Backward trajectory cluster analysis demonstrated that pollutant concentrations are substantially affected by both long-range transport mechanisms and localized anthropogenic sources. The assessment of health risks associated with metallic elements suggests a low risk to human health. These findings offer a crucial scientific foundation for air pollution management strategies in the SHZ region.

金属元素的来源和健康风险评估:对一个具有代表性的工业城市的研究。
空气中的PM2.5可以吸附多种物质,由于其体积小,可通过吸入将有毒有害物质带入人体,对人体健康有害。从2021年9月至2022年8月,在石河子地区采集PM2.5样本,对PM2.5中13种金属元素的分布及其潜在来源进行表征。调查结果显示,PM2.5浓度超过了35 μg/m3的国家阈值,同时地壳元素含量也有所上升。为了评估PM2.5中存在的13种金属元素的潜在来源,利用富集因子分析、主成分分析(PCA)和反向轨迹建模进行了综合分析。富集因子分析表明,五种元素受到人为活动的显著影响,其中镉的富集程度特别高。主成分分析表明,金属元素主要来自煤炭燃烧、车辆排放、粉尘、化石燃料燃烧和工业活动。反向轨迹聚类分析表明,污染物浓度受到远程输运机制和局域人为源的影响。与金属元素有关的健康风险评估表明,金属元素对人类健康的风险较低。这些研究结果为制定长沙地区空气污染管理策略提供了重要的科学依据。
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来源期刊
Environmental Geochemistry and Health
Environmental Geochemistry and Health 环境科学-工程:环境
CiteScore
8.00
自引率
4.80%
发文量
279
审稿时长
4.2 months
期刊介绍: Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people. Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes. The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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