Dushyant K Sharma, Salahuddeen Buhari, Divyanshi Soni, Susanta S Roy, Binson Babu
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引用次数: 0
Abstract
Strontium titanium perovskite oxide (SrTiO3, STO) has emerged as a promising material for energy applications, but its insulating nature limits its performance. Herein, a hierarchical structure of STO particles (600-700 nm) anchored onto reduced graphene oxide (rGO) is developed and their dual functionality in energy storage and water-splitting applications is evaluated. The STO-rGO composites exhibit enhanced high-power electrochemical performance in aqueous electrolytes, driven by their large electrochemical surface area and nondiffusion-controlled charge storage process. Furthermore, symmetric supercapacitors and asymmetric supercapacitors fabricated with STO-rGO composites demonstrate excellent electrochemical performance, achieving stable cycling stability with 90% and 95% capacity retention after 10,000 cycles, respectively, highlighting the potential of STO-rGO composites as high-power electrodes. Additionally, STO-rGO composites demonstrate superior oxygen evolution reaction activity, with a low overpotential of 303 mV, high mass activity, and an improved turnover frequency compared to pristine STO, with better long-term cycling stability, retaining performance after a 24 h chronopotentiometry test at a current density of 10 mA cm-2. This work demonstrates the dual functionality of strontium-based perovskite materials for energy storage and water-splitting applications, with significantly enhanced performance achieved through the incorporation of rGO.
期刊介绍:
ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
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