Electrodeposition and properties of Ni-Co-W-(Mo-Cu) high/medium entropy alloy coatings deposited from an aqueous bath

IF 4.3 2区材料科学 Q2 CHEMISTRY, PHYSICAL

Intermetallics Pub Date : 2025-03-18 DOI:10.1016/j.intermet.2025.108744

D. Ahmadkhaniha , D. Ascani , M. Fedel , C. Zanella

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引用次数: 0

Abstract

This study aimed to deposit multi-elemental coatings, including Ni-Co-Mo-W, Ni-Co-Cu-W and Ni-Co-Cu-Mo-W, with different configurational entropy from an aqueous bath by direct current electrodeposition. For this purpose, the effect of current density on the elemental composition was studied, and it was shown that the induced deposition of W was mainly controlled by Co, while the induced deposition of Mo was affected by both Ni and Co. In addition, Ni showed an activation deposition mechanism, while Mo suffered from concentration polarization for a prolonged electrodeposition process. All elements deposited homogeneously through the coatings' thickness except Cu showed some segregation. However, XRD spectra proved to have an amorphous structure for all coatings. Upon heat treatment, the crystallization of the coatings occurs, which results in an increase in hardness values from 5.6 to 11 GPa by increasing the heat treatment temperature up to 800 °C in the case of Ni-Co-Mo-W coating. The maximum hardness values were achieved at 500 °C in other coatings, and then a slight decrease was observed. Polarization results of the as-deposited coatings showed the potential for passivation of these coatings. However, due to the defects in the coatings, they were not completely protective towards the substrate. The results suggest that the presence of Cu had the main impact on the coating's properties since it decreased Co deposition, the hardness and the thermal stability of the coatings.

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来源期刊

Intermetallics 工程技术-材料科学：综合

CiteScore

7.80

自引率

9.10%

发文量

291

审稿时长

37 days

期刊介绍： This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys. The journal reports the science and engineering of metallic materials in the following aspects: Theories and experiments which address the relationship between property and structure in all length scales. Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations. Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties. Technological applications resulting from the understanding of property-structure relationship in materials. Novel and cutting-edge results warranting rapid communication. The journal also publishes special issues on selected topics and overviews by invitation only.