Methodical Approach to Studies of Magnetic Interaction of Fine Particles in an Aqueous Suspension Using Computer Simulation

Abstract

The need to increase the efficiency of mining operations determines the relevance of studying the properties of fine mineral particles for their extraction and reduction of environmental pollution. The development of approaches to studying the magnetic interaction of fine particles is of scientific and practical importance and is associated with complexity of calculating the superposition of their fields when solving the problem of controlling the magnetic properties of the suspension. The work describes a computer model of the dynamics of magnetic particle interaction developed with account for their aggregation under the impact of the magnetic dipole–dipole interaction and the destruction of aggregates during thermal (Brownian) motion in order to predict the magnetic properties of the suspension using the example of magnetite from deposits of the Zaimandrovskii iron ore region. The calculation shows that the electrostatic and dispersion interactions do not have a significant effect on the interaction dynamics of micron and submicron particles of magnetite with account for the experimentally measured zeta potential and the Hamaker’s constant. A procedure is developed for calibrating the computer model of the interaction dynamics of magnetic particles using the temperature dependence of the coefficient of translational diffusion of magnetite particles and the concentration dependence of the magnetic susceptibility of the suspension. An array of calculated values of the diffusion coefficient of the model particles and the initial magnetic susceptibility of their system is formed in a wide range of computer model parameters. A procedure is developed for linking the calculated and experimental data by varying the normalization parameters of the particle size, viscosity of the medium, and thermal energy in order to minimize the maximum discrepancy between the values. The necessity is established of taking into account the change in magnetic properties with a decrease in the size of magnetite particles during the calibration of the magnetic susceptibility of the model system. The developed methodological approach ensures good convergence of the calculated and experimental data and makes it possible to visualize the aggregation of the model particles as the result of dipole–dipole interactions. The developed computer model of the interaction dynamics of magnetic particles can be used to study the effect of an external magnetic field on the aggregation ability of fine magnetite particles in order to control their extraction in separation processes.