Thermodynamic Assessment of the Mg–La–Nd System

IF 1.5 4区 材料科学 Q4 CHEMISTRY, PHYSICAL
Tao Luo, Kai Zhu, Hongwei Xiong, Weisen Zheng, Jingya Wang, Xiao-Gang Lu
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引用次数: 0

Abstract

Ternary Mg–La–Nd and constituent binary Mg–La and Mg–Nd systems were assessed after a critical review of the experimental data and ab initio data using the CALPHAD method. The enthalpies of formation of the end-member compounds of the Mg(La, Nd) and Mg3(La, Nd) phases were obtained by ab initio calculations and then used to determine their model parameters. The binary Mg–La system was revised to maintain the consistency of the thermodynamic models, whereas the binary Mg–Nd system was reassessed to describe the homogeneity ranges of the hcp, dhcp, and Mg3Nd phases. Moreover, the metastable Mg12Nd phase was modeled to reproduce the phase constituents of the as-cast Mg–Nd alloys. Based on the updated binary descriptions, the ternary Mg–La–Nd system was assessed according to recent experimental data. Through a comprehensive comparison between the calculated and experimental phase equilibria and thermochemical property data, a reasonable agreement was achieved for the binary and ternary systems.

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来源期刊
Journal of Phase Equilibria and Diffusion
Journal of Phase Equilibria and Diffusion 工程技术-材料科学:综合
CiteScore
2.50
自引率
7.10%
发文量
70
审稿时长
1 months
期刊介绍: The most trusted journal for phase equilibria and thermodynamic research, ASM International''s Journal of Phase Equilibria and Diffusion features critical phase diagram evaluations on scientifically and industrially important alloy systems, authored by international experts. The Journal of Phase Equilibria and Diffusion is critically reviewed and contains basic and applied research results, a survey of current literature and other pertinent articles. The journal covers the significance of diagrams as well as new research techniques, equipment, data evaluation, nomenclature, presentation and other aspects of phase diagram preparation and use. Content includes information on phenomena such as kinetic control of equilibrium, coherency effects, impurity effects, and thermodynamic and crystallographic characteristics. The journal updates systems previously published in the Bulletin of Alloy Phase Diagrams as new data are discovered.
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