Vapor–Liquid Equilibrium Measurement of Methanol–Chloroform–Tetrahydrofuran and Methanol–Chloroform–Tetrahydrofuran–Dimethyl Sulfoxide Mixtures at 101.32 kPa
{"title":"Vapor–Liquid Equilibrium Measurement of Methanol–Chloroform–Tetrahydrofuran and Methanol–Chloroform–Tetrahydrofuran–Dimethyl Sulfoxide Mixtures at 101.32 kPa","authors":"V. I. Zhuchkov, V. M. Raeva, D. A. Ryzhkin","doi":"10.1134/S0036024424702509","DOIUrl":null,"url":null,"abstract":"<p><b>Abstract</b>—The vapor–liquid equilibrium of methanol–chloroform–tetrahydrofuran mixtures of various compositions and methanol–chloroform–tetrahydrofuran–dimethyl sulfoxide mixtures with different dimethyl sulfoxide contents at 101.32 kPa were studied experimentally. A comparison of experimental and calculated values of the relative volatility of substances in four-component mixtures was carried out. The results of extractive distillation of ternary mixtures are predicted based on experimental data and calculated data obtained using the NRTL model.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 1","pages":"29 - 37"},"PeriodicalIF":0.7000,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424702509","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract—The vapor–liquid equilibrium of methanol–chloroform–tetrahydrofuran mixtures of various compositions and methanol–chloroform–tetrahydrofuran–dimethyl sulfoxide mixtures with different dimethyl sulfoxide contents at 101.32 kPa were studied experimentally. A comparison of experimental and calculated values of the relative volatility of substances in four-component mixtures was carried out. The results of extractive distillation of ternary mixtures are predicted based on experimental data and calculated data obtained using the NRTL model.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.