Hydrochemical insights into spatiotemporal characteristics of groundwater salinization and health risk assessment of fluoride in the south bank of Yellow River irrigation area, Northwest China.
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Abstract
The groundwater salinization problem in the south bank of the Yellow River irrigation area is severe, restricting the sustainability of groundwater resources. However, the groundwater salinization formation mechanism is unclear. Accordingly, this study analyzed the chemical characteristics and salinization mechanism of groundwater based on hydrochemical analyses (self-organizing maps, SOM), isotope analyses (δ18O and δD), and quantitative models (Rayleigh distillation model), as well as evaluating the potential health risks of fluoride. The results indicated that surface water and groundwater in the study area had high salinity and weak alkalinity, with the fluoride and total nitrogen (TN) content exceeding Grade III water standards. Additionally, only 42% of the water samples were suitable for drinking, with nitrogen sources being the main cause of water quality deterioration. Around half of the samples were unsuitable for irrigation. The spatial and temporal distribution of total dissolved solids (TDS) in the irrigation area was influenced by autumn irrigation. Overall, groundwater salinization was primarily attributed to evaporite dissolution, cation exchange, silicate weathering, and human inputs. Evaporation was not the main influencing factor. In addition, the non-carcinogenic risk of fluoride in the water body decreased as follows: infants > children > adult females > adult males. The results of this study deepen understanding of the relationship between changes in groundwater quality and the ecological environment in semi-arid inland areas, thereby promoting the rational utilization and scientific management of groundwater resources in the irrigation area.
期刊介绍：
Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people.
Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes.
The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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