Benzothiadiazole-Based Dichroic Dyes: Novel Approaches for Electrically Tunable Liquid Crystal Smart Windows

IF 8 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Danyang Wan, Yongchi Ma, Juanli Li, Minggang Hu, Lexuan Liang, Lingchao Mo, Zhaoyi Che, Chen Tang, Kang Zhao, Hua Jiao, Jian Li
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Abstract

A series of benzothiadiazole (BT)-based dichroic dyes with donor–acceptor–donor (D–A–D) molecular frameworks is designed and synthesized, exhibiting absorption spectra that cover the visible light region and are tunable through molecular modifications. Most of the newly synthesized dyes show high dichroic ratios and order parameters, ensuring strong optical anisotropy and good alignment within the liquid crystal host mixture. The performance of individual dyes in smart window applications is evaluated, with transmittance changes observed under dynamic electric fields, demonstrating their potential for use in electrically tunable smart windows. To achieve full visible-light modulation, the combination of complementary absorption dyes is screened and an optimized mixture Mix-7 is obtained, which not only achieves full visible-light absorption coverage but also demonstrates smooth and dynamic transmittance modulation under varying voltages. Finally, a prototype smart window filled with Mix-7 is fabricated to validate the continuous tunability of dye-doped liquid crystal-based systems. Additionally, further introduction of a polarizer film significantly reduces the transmittance of the demo, especially in the OFF state which presents an almost completely dark state, highlighting the potential for automotive smart window applications.

Abstract Image

我们设计并合成了一系列基于苯并噻二唑(BT)的二向色染料,它们具有供体-受体-供体(D-A-D)分子框架,其吸收光谱覆盖了可见光区域,并可通过分子修饰进行调整。大多数新合成的染料都显示出较高的二向色比和有序参数,从而确保了液晶主混合物内较强的光学各向异性和良好的配位。通过观察动态电场下的透射率变化,评估了单个染料在智能窗口应用中的性能,证明了它们在电可调智能窗口中的应用潜力。为了实现完全的可见光调制,对互补吸收染料的组合进行了筛选,并得到了优化的混合物 Mix-7,它不仅实现了完全的可见光吸收覆盖,而且在不同电压下显示出平滑和动态的透射率调制。最后,制作了一个填充了 Mix-7 的智能窗口原型,以验证基于染料掺杂液晶系统的连续可调性。此外,偏振片薄膜的进一步引入大大降低了演示的透射率,尤其是在关闭状态下,几乎呈现全黑状态,这凸显了汽车智能车窗应用的潜力。
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来源期刊
Advanced Optical Materials
Advanced Optical Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-OPTICS
CiteScore
13.70
自引率
6.70%
发文量
883
审稿时长
1.5 months
期刊介绍: Advanced Optical Materials, part of the esteemed Advanced portfolio, is a unique materials science journal concentrating on all facets of light-matter interactions. For over a decade, it has been the preferred optical materials journal for significant discoveries in photonics, plasmonics, metamaterials, and more. The Advanced portfolio from Wiley is a collection of globally respected, high-impact journals that disseminate the best science from established and emerging researchers, aiding them in fulfilling their mission and amplifying the reach of their scientific discoveries.
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