Kinetics of Reduction by Carbon from Special Coke Used in Electrothermal Silicon Production for the C–Fe–O System

IF 0.4 Q4 ENGINEERING, CHEMICAL
G. A. Ulyeva
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引用次数: 0

Abstract

Kinetic features of the carbon in rexil special coke obtained from long-flame Shubarkol coal and used for electrothermal production of silicon are outlined. For the example of the C–Fe–O system, it is found that, in comparison with other reducing agents (graphite, blast furnace coke), rexil is characterized by high reaction rate and activation energy. Experimental and industrial tests regarding silicon production from ore in electric furnaces indicate that practically all of the charcoal in the batch may be replaced by rexil. For example, when the ratio of rexil and coal (in terms of fixed carbon Cso) is 80 : 20, the furnace productivity is increased, the degree of silicon extraction (91%) is increased, and the mean silicon content (97.8%) is increased.

Abstract Image

概述了从长焰舒巴科尔煤中提取并用于电热法生产硅的 rexil 特殊焦炭中碳的动力学特征。以 C-Fe-O 系统为例,研究发现,与其他还原剂(石墨、高炉焦炭)相比,rexil 的特点是反应速度快、活化能高。有关在电炉中从矿石中生产硅的实验和工业测试表明,批次中的木炭几乎都可以用 rexil 替代。例如,当雷克西尔和煤的比例(以固定碳 Cso 计)为 80 : 20 时,电炉的生产率提高了,硅的提取率(91%)提高了,平均硅含量(97.8%)提高了。
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来源期刊
Coke and Chemistry
Coke and Chemistry ENGINEERING, CHEMICAL-
CiteScore
0.70
自引率
50.00%
发文量
36
期刊介绍: The journal publishes scientific developments and applications in the field of coal beneficiation and preparation for coking, coking processes, design of coking ovens and equipment, by-product recovery, automation of technological processes, ecology and economics. It also presents indispensable information on the scientific events devoted to thermal rectification, use of smokeless coal as an energy source, and manufacture of different liquid and solid chemical products.
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