{"title":"Investigation of real-world second-order singular differential equations by optimal homotopy analysis technique","authors":"Randhir Singh, Prabal Datta, Vandana Guleria, Nirupam Sahoo","doi":"10.1007/s10910-025-01703-2","DOIUrl":null,"url":null,"abstract":"<div><p>Extensive studies have investigated second-order singular differential equations to model various phenomena in astrophysics, reaction-diffusion processes, and electrohydrodynamics. However, finding numerical and analytical solutions for these problems with appropriate boundary conditions is challenging due to their inherent nonlinearity. Our current study explores singular second-order differential equations (SSODEs) with boundary conditions, specifically those modelling the distribution of heat sources in the human head and the steady-state temperature distribution in a vessel before a thermal explosion. The fundamental idea behind our approach is initially transforming the differential equation into an equivalent integral form, thereby circumventing the singular behaviour. Subsequently, the optimal homotopy analysis method is employed to scrutinize two distinct models, i.e., the heat conduction model, the thermal explosion model and the spherical catalyst equation. Further, a detailed convergence analysis is conducted in a Banach space framework to ensure the method’s reliability. The accuracy of the new approach is checked by considering various numerical examples with different values of thermogenesis heat production, the Biot number, and metabolic thermogenesis slope. It has been shown that the proposed approach qualitatively and quantitatively approximates the solutions with higher precision than the existing Adomian decomposition method.</p></div>","PeriodicalId":648,"journal":{"name":"Journal of Mathematical Chemistry","volume":"63 4","pages":"962 - 981"},"PeriodicalIF":1.7000,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Mathematical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10910-025-01703-2","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Extensive studies have investigated second-order singular differential equations to model various phenomena in astrophysics, reaction-diffusion processes, and electrohydrodynamics. However, finding numerical and analytical solutions for these problems with appropriate boundary conditions is challenging due to their inherent nonlinearity. Our current study explores singular second-order differential equations (SSODEs) with boundary conditions, specifically those modelling the distribution of heat sources in the human head and the steady-state temperature distribution in a vessel before a thermal explosion. The fundamental idea behind our approach is initially transforming the differential equation into an equivalent integral form, thereby circumventing the singular behaviour. Subsequently, the optimal homotopy analysis method is employed to scrutinize two distinct models, i.e., the heat conduction model, the thermal explosion model and the spherical catalyst equation. Further, a detailed convergence analysis is conducted in a Banach space framework to ensure the method’s reliability. The accuracy of the new approach is checked by considering various numerical examples with different values of thermogenesis heat production, the Biot number, and metabolic thermogenesis slope. It has been shown that the proposed approach qualitatively and quantitatively approximates the solutions with higher precision than the existing Adomian decomposition method.
期刊介绍:
The Journal of Mathematical Chemistry (JOMC) publishes original, chemically important mathematical results which use non-routine mathematical methodologies often unfamiliar to the usual audience of mainstream experimental and theoretical chemistry journals. Furthermore JOMC publishes papers on novel applications of more familiar mathematical techniques and analyses of chemical problems which indicate the need for new mathematical approaches.
Mathematical chemistry is a truly interdisciplinary subject, a field of rapidly growing importance. As chemistry becomes more and more amenable to mathematically rigorous study, it is likely that chemistry will also become an alert and demanding consumer of new mathematical results. The level of complexity of chemical problems is often very high, and modeling molecular behaviour and chemical reactions does require new mathematical approaches. Chemistry is witnessing an important shift in emphasis: simplistic models are no longer satisfactory, and more detailed mathematical understanding of complex chemical properties and phenomena are required. From theoretical chemistry and quantum chemistry to applied fields such as molecular modeling, drug design, molecular engineering, and the development of supramolecular structures, mathematical chemistry is an important discipline providing both explanations and predictions. JOMC has an important role in advancing chemistry to an era of detailed understanding of molecules and reactions.