Synthesis and structural characterization of two novel cyano/isocyano bridged CuI coordination polymers: Catalytic activities in the synthesis of triazoles

IF 2.7 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Inorganica Chimica Acta Pub Date : 2025-03-07 DOI:10.1016/j.ica.2025.122637

Hadi Kargar , Roberto Centore , Mehdi Fallah-Mehrjardi , Emanuela Santagat , Emmanuele Parisi , Khurram Shahzad Munawar

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Abstract

In the present study, two novel polymeric copper(I) cyanide/isocyanide complexes with N,N′-bidentate Schiff base ligands ([Cu(L^Br)CN]_n and [Cu(L^Cl)CN]_n) were successfully synthesized and characterized by employing FT-IR and elemental analysis. The single-crystal X-ray diffraction (SC-XRD) analysis was used to figure out the geometrical properties of the complexes, and the results showed that the copper ions are attached to N atoms of Schiff base ligands. The bond angles surrounding the Cu(I) ions revealed the distorted tetrahedral geometry of the complexes. Furthermore, the catalytic ability of these complexes was evaluated in the synthesis of triazoles under a conventional thermal environment.

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来源期刊

Inorganica Chimica Acta 化学-无机化学与核化学

CiteScore

6.00

自引率

3.60%

发文量

440

审稿时长

35 days

期刊介绍： Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews. Topics covered include: • chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies; • synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs); • reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models; • applications of inorganic compounds, metallodrugs and molecule-based materials. Papers composed primarily of structural reports will typically not be considered for publication.