{"title":"Methods for Synthesis of PbIn1/2Ta1/2O3 with the Perovskite Structure","authors":"A. A. Gusev, I. P. Raevski","doi":"10.1134/S002016852470122X","DOIUrl":null,"url":null,"abstract":"<p>We have studied the effect of mechanical activation on the synthesis of lead indium tantalate and the formation of the perovskite and pyrochlore phases during both mechanochemical synthesis and subsequent firing. To reduce the electrical conductivity of resulting ceramics, lithium carbonate was added to starting mixtures, which is known to stabilize the perovskite structure. PbIn<sub>1/2</sub>Ta<sub>1/2</sub>O<sub>3</sub> samples were prepared in the presence of 1–3 wt % superstoichiometric lithium carbonate at firing times from 30 min to 2 h. We have found conditions that ensure the preparation of single-phase material with the perovskite structure in the presence of lithium carbonate additions at different firing temperatures. The sequence in which reagents are introduced into the starting mixture and their activation have been shown to have a significant effect on the synthesis of the tantalate and the formation of the perovskite phase. We have compared a number of sample preparation procedures differing in mechanical activation conditions and the way in which the starting materials are introduced. Optimal conditions have been found which ensure the preparation of piezoceramics containing the maximum amount of the perovskite phase and having the highest density.</p>","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"60 8","pages":"970 - 975"},"PeriodicalIF":0.9000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S002016852470122X","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We have studied the effect of mechanical activation on the synthesis of lead indium tantalate and the formation of the perovskite and pyrochlore phases during both mechanochemical synthesis and subsequent firing. To reduce the electrical conductivity of resulting ceramics, lithium carbonate was added to starting mixtures, which is known to stabilize the perovskite structure. PbIn1/2Ta1/2O3 samples were prepared in the presence of 1–3 wt % superstoichiometric lithium carbonate at firing times from 30 min to 2 h. We have found conditions that ensure the preparation of single-phase material with the perovskite structure in the presence of lithium carbonate additions at different firing temperatures. The sequence in which reagents are introduced into the starting mixture and their activation have been shown to have a significant effect on the synthesis of the tantalate and the formation of the perovskite phase. We have compared a number of sample preparation procedures differing in mechanical activation conditions and the way in which the starting materials are introduced. Optimal conditions have been found which ensure the preparation of piezoceramics containing the maximum amount of the perovskite phase and having the highest density.
期刊介绍:
Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.