Synthesis and structure of {Mo2O2S2} cluster compounds with pyrazole ligands
IF 2.4
3区 化学
Q2 CHEMISTRY, INORGANIC & NUCLEAR
引用次数: 0
Abstract
Extending the family of oxothiomolybdates, the interaction of (pzH2)2[Mo2O2S2(H2O)2(C2O4)2] with pyrazole (pzH) at different reaction conditions in a sealed glass ampoules was studied. Varying reaction temperature (120–150 °C) and time (24–48 h), the formation of a binuclear cluster (pzH2)2[anti-Mo2O2S2(pzH)2(C2O4)2], dimer [{Mo2O2S2(pzH)3}2(C2O4)2], dimer [{Mo2O2.765S1.235(pzH)3}2(C2O4)2] and complex compound [Mo8S6O12(pzH)6(pz)6] is observed. The last compounds in this series are formed simultaneously with the decomposition of the cluster complex. The composition and structure of the compounds have been determined by elemental analysis and powder and/or single-crystal X-ray diffraction analysis.
求助全文
约1分钟内获得全文
求助全文
来源期刊
Polyhedron
化学-晶体学
CiteScore
4.90
自引率
7.70%
发文量
515
审稿时长
2 months
期刊介绍：
Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry.
Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
