Johanna A. de Jong, Mark S. Workentin, Mahdi Hesari
{"title":"Charge State Tuning and Photochemical Stability of Au25(SR)18 Nanoclusters","authors":"Johanna A. de Jong, Mark S. Workentin, Mahdi Hesari","doi":"10.1002/cptc.202400236","DOIUrl":null,"url":null,"abstract":"<p>The photolysis of the gold nanoclusters Au<sub>25</sub>(SR)<sub>18</sub><sup>z</sup> (R=C<sub>2</sub>H<sub>4</sub>Ph and C<sub>12</sub>H<sub>25</sub>, z=1−, 0 and 1+) NCs in halogenated solvents such as dichloromethane leads to changes in the charged states of the Au<sub>25</sub>(SR)<sub>18</sub><sup>z</sup> observed using UV-Visible and <sup>1</sup>H NMR spectroscopic techniques. Matrix-assisted laser desorption/ionization mass spectrometry results proved that during charge transformation from anion to neutral and eventually cation forms, the size of nanoclusters remains intact. Electrochemistry of Au<sub>25</sub>(SR)<sub>18</sub> has enabled the monitoring of these changes by cyclic voltammetry, indicating decay in the redox peak current upon irradiation. In the absence of light and/or in a non-halogenated solvent, e. g., tetrahydrofuran, no substantial change in the photophysical signatures of Au<sub>25</sub> nanoclusters was observed. These observations highlight the importance of selecting appropriate solvent(s) in the synthesis and photochemical studies of atomically precise metal nanoclusters and the possibility of using photochemistry in halogenated solvents to synthesize different charge states of atomically precise metal nanoclusters. Thus, other monodispersed molecule-like nanoclusters, with various sizes and charges, can be achieved via this photosynthetic protocol under controlled conditions, e. g., solvent, light, and photolysis duration.</p>","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"9 3","pages":""},"PeriodicalIF":3.0000,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemPhotoChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cptc.202400236","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The photolysis of the gold nanoclusters Au25(SR)18z (R=C2H4Ph and C12H25, z=1−, 0 and 1+) NCs in halogenated solvents such as dichloromethane leads to changes in the charged states of the Au25(SR)18z observed using UV-Visible and 1H NMR spectroscopic techniques. Matrix-assisted laser desorption/ionization mass spectrometry results proved that during charge transformation from anion to neutral and eventually cation forms, the size of nanoclusters remains intact. Electrochemistry of Au25(SR)18 has enabled the monitoring of these changes by cyclic voltammetry, indicating decay in the redox peak current upon irradiation. In the absence of light and/or in a non-halogenated solvent, e. g., tetrahydrofuran, no substantial change in the photophysical signatures of Au25 nanoclusters was observed. These observations highlight the importance of selecting appropriate solvent(s) in the synthesis and photochemical studies of atomically precise metal nanoclusters and the possibility of using photochemistry in halogenated solvents to synthesize different charge states of atomically precise metal nanoclusters. Thus, other monodispersed molecule-like nanoclusters, with various sizes and charges, can be achieved via this photosynthetic protocol under controlled conditions, e. g., solvent, light, and photolysis duration.
ChemPhotoChemChemistry-Physical and Theoretical Chemistry
CiteScore
5.80
自引率
5.40%
发文量
165
期刊介绍:
Light plays a crucial role in natural processes and leads to exciting phenomena in molecules and materials. ChemPhotoChem welcomes exceptional international research in the entire scope of pure and applied photochemistry, photobiology, and photophysics. Our thorough editorial practices aid us in publishing authoritative research fast. We support the photochemistry community to be a leading light in science.
We understand the huge pressures the scientific community is facing every day and we want to support you. Chemistry Europe is an association of 16 chemical societies from 15 European countries. Run by chemists, for chemists—we evaluate, publish, disseminate, and amplify the scientific excellence of chemistry researchers from around the globe.