Photoinduced Reductive Cyclization of 2-Nitroaryl-Tethered Carbonyl Compounds: An Approach to Access Nitrogen-Fused Heterocycles

IF 4.6 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2025-03-11 DOI:10.1039/d5qo00363f

Yu-Long Du, Yuhui Wu, Jiarui Tang, Jianhui Chen, Yanshu Luo, Yuanzhi Xia

引用次数: 0

Abstract

In the presence of AcSH and DIPEA, a photo-induced reductive cyclization reaction of 2-nitroaryl-tethered carbonyl compounds was achieved, affording a mild method for the preparation of N-fused heterocycles including quinoline, quinoxaline, oxazine, quinazolinone, and indolone. Preliminary mechanistic studies suggested that this catalyst -free transformation was triggered by a visible-light induced EDA complex-based SET reduction process.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.