M. A. Sukharenko, I. S. Portnova, A. S. Egorova, I. K. Garkushin, I. M. Kondratyuk
{"title":"Phase Equilibria in the LiF–KCl–KBr–LiKCrO4 Stable Tetrahedron of the Quinary Reciprocal System Li+,K+||F–,Cl–,Br–,\\({\\text{CrO}}_{4}^{{2 - }}\\)","authors":"M. A. Sukharenko, I. S. Portnova, A. S. Egorova, I. K. Garkushin, I. M. Kondratyuk","doi":"10.1134/S0020168524701115","DOIUrl":null,"url":null,"abstract":"<p>We have studied the LiF–KCl–KBr–LiKCrO<sub>4</sub> stable tetrahedron of the quinary reciprocal system Li<sup>+</sup>,K<sup>+</sup>||F<sup>–</sup>,Cl<sup>–</sup>,Br<sup>–</sup>,<span>\\({\\text{CrO}}_{4}^{{2 - }}\\)</span>. According to experimental data obtained by differential thermal analysis, three solid phases crystallize in the stable tetrahedron: LiF, LiKCrO<sub>4</sub>, and a continuous series of KCl<sub><i>x</i></sub>Br<sub>1–<i>x</i></sub> solid solutions. The solid solutions are stable, and there are no invariant equilibrium points.</p>","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"60 7","pages":"886 - 891"},"PeriodicalIF":0.9000,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S0020168524701115","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We have studied the LiF–KCl–KBr–LiKCrO4 stable tetrahedron of the quinary reciprocal system Li+,K+||F–,Cl–,Br–,\({\text{CrO}}_{4}^{{2 - }}\). According to experimental data obtained by differential thermal analysis, three solid phases crystallize in the stable tetrahedron: LiF, LiKCrO4, and a continuous series of KClxBr1–x solid solutions. The solid solutions are stable, and there are no invariant equilibrium points.
期刊介绍:
Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.