Mint synthesized r-GO intercalated SnO2 nanocomposites for textile dye degradation

C. Amudha, M. Santhi
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Abstract

The purpose of this work was to explore the efficacy of tin oxide (SnO2) with reduced graphene oxide (r-GO) Nanocomposites (NCs) in terms of their photocatalytic activity. The preparation of pure r-GO sheets and SnO2/r-GO NCs was accomplished by the use of the one-pot green method. Several imaging and spectroscopic methods, including as X-ray diffraction (XRD), photoluminescence (PL), UV–Vis spectroscopy, Fourier transform infrared (FTIR), transmission electron microscopy (TEM), and Raman scattering microscopy, were used in order to describe the materials that were synthesized. Following the addition of r-GO, the crystallite size of the SnO2 nanoparticles increased. Using transmission electron microscopy, it was discovered that the SnO2 nanoparticles were securely linked to the r-GO sheets. According to the results of the optical experiments, the bandgap energy of the SnO2/r-GO NCs was slightly lower when compared to the energy of the pure r-GO sheet. After r-GO doping, the PL spectra of the SnO2/r-GO NCs were found to be less intense compared to those of pure r-GO. This indicates that the recombination rate of the surface charges (e/h+) reduced. The results of this study indicate that the degrading efficiency of SnO2/r-GO NCs was nearly twice as high as that of methyl orange (MO) dye, which was 99%. This is in comparison to the 95% efficiency of pure r-GO. A unique strategy for enhancing the photocatalytic effectiveness of SnO2 nanoparticles is suggested in this study. This strategy involves fusing graphene derivatives with SnO2 nanoparticles.
薄荷合成了氧化石墨烯嵌层氧化锡纳米复合材料用于纺织染料降解
本研究的目的是探讨氧化锡(SnO2)与还原氧化石墨烯(r-GO)纳米复合材料(nc)在光催化活性方面的效果。采用一锅绿法制备了纯氧化石墨烯薄片和SnO2/氧化石墨烯纳米管。利用x射线衍射(XRD)、光致发光(PL)、紫外可见光谱(UV-Vis)、傅里叶变换红外(FTIR)、透射电子显微镜(TEM)和拉曼散射显微镜等多种成像和光谱方法对所合成的材料进行了表征。加入r-GO后,SnO2纳米颗粒的晶粒尺寸增大。通过透射电子显微镜,发现SnO2纳米颗粒与r-GO薄片安全连接。光学实验结果表明,SnO2/r-GO纳米材料的带隙能量略低于纯r-GO薄片的带隙能量。掺入r-GO后,SnO2/r-GO纳米材料的PL光谱强度低于纯r-GO纳米材料。这表明表面电荷(e−/h+)的复合速率降低了。本研究结果表明,SnO2/r-GO NCs的降解效率几乎是甲基橙(MO)染料的两倍,达到99%。相比之下,纯r-GO的效率为95%。本研究提出了一种提高SnO2纳米颗粒光催化效能的独特策略。该策略包括将石墨烯衍生物与SnO2纳米颗粒融合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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CiteScore
2.70
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