Manifestations of Fouling of Heterogeneous Membranes by Components of Wine Materials in the Process of Their Tartrate Stabilization by Electrodialysis

IF 2 Q4 CHEMISTRY, PHYSICAL

Membranes and Membrane Technologies Pub Date : 2025-03-06 DOI:10.1134/S2517751624600808

E. L. Pasechnaya, M. A. Ponomar, A. V. Klevtsova, K. A. Kirichenko, K. V. Solonchenko, N. D. Pismenskaya

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Abstract

Tartrate stabilization of wine materials by electrodialysis makes it possible to speed up and automate this process and reduce the loss of valuable components. Widespread implementation of electrodialysis in industrial wine production is hampered by fouling of ion-exchange membranes with wine components and by the very limited range of membranes currently used. This study is devoted to a comparative analysis of properties of relatively inexpensive heterogeneous ion-exchange membranes MA-41, MK-40, AMH-PES, and CMH-PES before and after their use in tartrate stabilization of wine materials by electrodialysis. It is shown that the mechanisms of fouling and its effect on transport characteristics, as well as on the development of electroconvection and generation of H⁺ and OH^– ions, are largely determined by counterions that are transferred through cation-exchange (transition metal cations) and anion-exchange (carboxylic acid anions) membranes. Membranes MA-41 and MK-40 demonstrate higher resistance to fouling during operation of an electrodialysis device for less than 15 h.

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电渗析稳定酒石酸盐过程中酒料组分对非均相膜污染的表现

通过电渗析使酒石酸盐稳定葡萄酒材料，可以加快和自动化这一过程，并减少有价值的成分的损失。电渗析在工业葡萄酒生产中的广泛实施受到离子交换膜与葡萄酒成分的污染和目前使用的膜范围非常有限的阻碍。本研究对相对廉价的多相离子交换膜MA-41、MK-40、AMH-PES和CMH-PES在电渗析法稳定酒石酸盐酒料中使用前后的性能进行了比较分析。研究表明，污染的机制及其对传输特性的影响，以及对电对流的发展和H+和OH -离子的产生的影响，在很大程度上取决于通过阳离子交换（过渡金属阳离子）和阴离子交换（羧酸阴离子）膜转移的反离子。MA-41和MK-40膜在电渗析装置操作少于15小时时表现出更高的抗污染能力。

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来源期刊

Membranes and Membrane Technologies Multiple-

CiteScore

3.10

自引率

31.20%

发文量

期刊介绍： The journal Membranes and Membrane Technologies publishes original research articles and reviews devoted to scientific research and technological advancements in the field of membranes and membrane technologies, including the following main topics:novel membrane materials and creation of highly efficient polymeric and inorganic membranes;hybrid membranes, nanocomposites, and nanostructured membranes;aqueous and nonaqueous filtration processes (micro-, ultra-, and nanofiltration; reverse osmosis);gas separation;electromembrane processes and fuel cells;membrane pervaporation and membrane distillation;membrane catalysis and membrane reactors;water desalination and wastewater treatment;hybrid membrane processes;membrane sensors;membrane extraction and membrane emulsification;mathematical simulation of porous structures and membrane separation processes;membrane characterization;membrane technologies in industry (energy, mineral extraction, pharmaceutics and medicine, chemistry and petroleum chemistry, food industry, and others);membranes and protection of environment (“green chemistry”).The journal has been published in Russian already for several years, English translations of the content used to be integrated in the journal Petroleum Chemistry. This journal is a split off with additional topics.