Investigating the reparability of fusion bonded metal-plastic composites for improved circularity

Christian Gundlach , Klaus Dilger , Sven Hartwig
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Abstract

Multi-material structures have long been established for various components in the automotive industry in the context of lightweight construction, with metal and fiber-reinforced plastic in particular being advantageously joined together in the form of so-called hybrid designs. The joining technology plays a decisive role here with regard to the hybrid component's performance and aging resistance. However, the complexity of component manufacture and the feasibility of subsequent repair, reprocessing and recycling concepts are largely determined by the choice of joining technology. The aim of the present work is to investigate the reparability of joints produced fusion bonding on a fundamental level. Lap shear specimens consisting of a laser-structured, metallic joining partner and a fiber-reinforced thermoplastic (FRTP) sheet are used as a basis for evaluation. The test sequence comprises an initial joining and three consecutive repair processes of the joint by means of fusion bonding, with a destructive lap shear test taking place after each joining process. Two repair approaches (with and without an additional polyamide-6 film) are investigated. Over three repair processes, a slightly decreasing trend in lap shear strength is found if the repair is carried out without additional polyamide-6 film. Using a polyamide-6 film during the repair leads to higher strength in every case tested. Thermal analysis and microindentation on the FRTP substrate takes place in order to quantify the influence of the heating required for repair. A negative effect on the degree of crystallinity and the strength of the polyamide-6 matrix close to the steel-FRTP interface is found. Nevertheless, based on the criteria derived from DIN EN 45554, the conclusion is drawn that the reparability of metal-FRTP joints produced by fusion bonding is possible on a sample scale. For future work, a more in-depth study of the joining surfaces, especially the metal part, as well as the inclusion of an aging step before each lap shear test should be considered.
研究提高金属-塑料复合材料圆度的可修复性
长期以来,在轻量化结构的背景下,汽车工业的各种部件已经建立了多材料结构,特别是金属和纤维增强塑料以所谓的混合设计的形式有利地结合在一起。连接技术对混合材料的性能和抗老化性能起着决定性的作用。然而,部件制造的复杂性以及后续维修、再加工和回收概念的可行性在很大程度上取决于连接技术的选择。本工作的目的是在一个基本的水平上研究产生融合连接的关节的可修复性。由激光结构、金属连接伙伴和纤维增强热塑性塑料(FRTP)板组成的搭接剪切试样被用作评估的基础。试验序列包括初始连接和通过熔合对接头进行连续三次修复过程,每次连接过程后进行破坏性搭接剪切试验。研究了两种修复方法(有和没有额外的聚酰胺-6膜)。在三次修复过程中,如果不添加聚酰胺-6膜进行修复,则搭接剪切强度略有下降。在修复过程中使用聚酰胺-6薄膜,在每个测试案例中都可以获得更高的强度。在FRTP基板上进行热分析和微压痕是为了量化修复所需加热的影响。在接近钢- frtp界面处,聚酰胺-6基体的结晶度和强度受到不利影响。然而,根据DIN EN 45554的标准,得出的结论是,在样品规模上,熔合生产的金属- frtp接头的可修复性是可能的。对于未来的工作,更深入地研究连接面,特别是金属部分,以及在每次搭接剪切试验之前包含一个老化步骤,应该考虑。
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