M. Malyaadri, K. Jagadeeswaraiah, T. Narasimha murthy, PRG. Nallappa reddy
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引用次数: 0
Abstract
A series of Mg/Al/La mixed oxide catalysts were synthesized using an alkali-free coprecipitation method and calcined at various temperatures. The catalysts were characterized using Fourier transform infrared spectroscopy, X-ray diffraction, and temperature-programmed desorption of CO2. These catalysts were evaluated for transesterification of glycerol with dimethyl carbonates to yield glycerol carbonates. The catalyst with an Mg : Al : La weight ratio of 3 : 1 : 1 demonstrated optimum performance in the formation of glycerol carbonates and exhibited excellent activity even at 75°C. However, its activity decreased during recycling. The effects of various parameters, such as reaction temperature, catalyst concentration, and the molar ratio of glycerol to dimethyl carbonates, were studied to optimize the reaction conditions.
期刊介绍：
Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.
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