Metathesis of Lower Olefins on Molybdenum Oxide Catalysts

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Kinetics and Catalysis Pub Date : 2025-02-25 DOI:10.1134/S0023158424602341

A. I. Nikiforov, E. A. Chesnokov, A. G. Popov, I. A. Kasyanov, Z. S. Enbaev, I. A. Nikiforov, I. I. Ivanova

引用次数: 0

Abstract

The review is devoted to an analysis of the metathesis of lower olefins on molybdenum-containing heterogeneous catalysts. Individual aspects of the cross-metathesis reaction are analyzed: the main industrial processes based on metathesis are described, the kinetic and thermodynamic issues of the reaction are considered, and the mechanisms of individual stages are discussed. The relationship between the structure of catalysts and their catalytic activity is demonstrated. Particular attention in this review is given to methods for improving catalytic systems based on molybdenum oxide.

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低烯烃在氧化钼催化剂上的复分解

本文对低烯烃在含钼非均相催化剂上的复分解进行了分析。对交叉复分解反应的各个方面进行了分析：描述了基于交叉复分解的主要工业过程，考虑了反应的动力学和热力学问题，并讨论了各个阶段的机理。证明了催化剂的结构与其催化活性之间的关系。本文着重介绍了改进氧化钼催化体系的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Kinetics and Catalysis 化学-物理化学

CiteScore

2.10

自引率

27.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.