{"title":"Industrially Promising Catalytic Processes Involving Molybdovanadophosphoric Heteropoly Acid Solutions","authors":"Yu. A. Rodikova, E. G. Zhizhina","doi":"10.1134/S0023158424602377","DOIUrl":null,"url":null,"abstract":"<p>The review discusses the most significant catalytic processes involving solutions of Mo–V–P heteropoly acids (HPA-<i>x</i>, where <i>x</i> is the number of V atoms), which have been developed at Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences. The prospects for using modified HPA-<i>x</i> solutions as oxidation and bifunctional catalysts are shown. The unique thermal stability and oxidation capacity of these systems make it possible to approach the implementation of optimum routes to synthesizing substances exhibiting activity in delignification, the development of highly selective key stages of the synthesis of vitamins K and E, and the neutralization of highly toxic gases (CO) without their predrying.</p>","PeriodicalId":682,"journal":{"name":"Kinetics and Catalysis","volume":"65 6","pages":"605 - 622"},"PeriodicalIF":1.3000,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Kinetics and Catalysis","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0023158424602377","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The review discusses the most significant catalytic processes involving solutions of Mo–V–P heteropoly acids (HPA-x, where x is the number of V atoms), which have been developed at Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences. The prospects for using modified HPA-x solutions as oxidation and bifunctional catalysts are shown. The unique thermal stability and oxidation capacity of these systems make it possible to approach the implementation of optimum routes to synthesizing substances exhibiting activity in delignification, the development of highly selective key stages of the synthesis of vitamins K and E, and the neutralization of highly toxic gases (CO) without their predrying.
期刊介绍：
Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.
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