Design and Control of Polymeric Network Architectures Based on Network Dimension Theory

IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL
Hidetaka Tobita
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引用次数: 0

Abstract

A new design policy to synthesize nanogel molecules having desired dimensions under unperturbed state is proposed. Miniemulsion copolymerization of vinyl and divinyl monomers, both conventional free-radical polymerization and ideal living polymerization, is used to illustrate the method. For the network formation dynamics, the newly proposed model that takes into account the size and structure dependence of cross-linking/cyclization reactions is employed. The master curve relationship that indicates the maximum average dimensions for randomly cross-linked networks is used as a guideline and the network dimension is controlled by the magnitude of network maturity index NMI, which is the average number of cycle rank per primary chain. By appropriately sizing the NMI, it is possible to synthesize network polymers with dimensions equal to or greater than the maximum dimensions achievable with a homogeneous, randomly cross-linked network polymer of the same cycle rank and molecular weight. The current strategy of designing and controlling 3D size is applicable regardless of the reaction mechanism of network formation and will also be applied to the synthesis of macro-gels.

Abstract Image

基于网络维数理论的聚合物网络结构设计与控制
提出了一种在无摄动状态下合成具有理想尺寸的纳米凝胶分子的新设计策略。以乙烯基和二乙烯基单体的微乳液共聚为例,分别采用常规自由基聚合和理想活性聚合两种方法。对于网络形成动力学,采用了考虑交联/环化反应的大小和结构依赖性的新模型。以表示随机交联网络最大平均维数的主曲线关系为指导,网络维数由网络成熟度指数NMI的大小(即每个主链的平均循环秩数)控制。通过适当调整NMI的尺寸,可以合成尺寸等于或大于相同循环阶和分子量的均匀、随机交联网络聚合物所能达到的最大尺寸的网络聚合物。目前设计和控制三维尺寸的策略适用于无论网络形成的反应机理如何,也将应用于宏观凝胶的合成。
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来源期刊
Macromolecular Reaction Engineering
Macromolecular Reaction Engineering 工程技术-高分子科学
CiteScore
2.60
自引率
20.00%
发文量
55
审稿时长
3 months
期刊介绍: Macromolecular Reaction Engineering is the established high-quality journal dedicated exclusively to academic and industrial research in the field of polymer reaction engineering.
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