The Use of Weakly Basic Ion Exchange Resin Amberlite IRA-68 for the Chromatographic Separation of Rare Earth Elements

IF 1.2 4区化学 Q4 BIOCHEMICAL RESEARCH METHODS

Chromatographia Pub Date : 2024-12-13 DOI:10.1007/s10337-024-04380-6

Zbigniew Samczyński

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引用次数: 0

Abstract

The possibility of applying the system: weakly basic Amberlite IRA-68 resin-nitrilotriacetic acid (NTA) solutions for the separation of rare earth elements (REE) by ion exchange chromatography was investigated. Preliminary research results revealed that the affinity of REE towards the ion exchanger is closely correlated with the stability of their negative complexes that they form with NTA. Three separate groups of lanthanides could be distinguished, i.e. light (La, Ce, Pr, Nd), medium (Y, Sm, Eu, Gd, Tb, Dy, Ho, Er) and heavy (Tm, Yb, Lu, Sc). Moreover, it seemed that within the first and third groups it was possible to individually separate elements from each other. Based on the experimentally obtained relationships, the theoretically assumed course of the ion exchange reaction of anionic REE complexes with NTA on the Amberlite IRA-68 resin was confirmed. The influence of the ion exchanger particle size, column size and composition of the mobile phase, i.e. pH, NTA and neutral salt (NaNO₃) concentration, on the chromatographic separation of REE was investigated. It has been shown that the proper selection of these parameters makes it possible not only to divide REE into the three groups mentioned above, but also to individually separate some elements, i.e. La, Ce, Pr, Nd, Tm, Yb, Lu and Sc.

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来源期刊

Chromatographia 化学-分析化学

CiteScore

3.40

自引率

5.90%

发文量

103

审稿时长

2.2 months

期刊介绍： Separation sciences, in all their various forms such as chromatography, field-flow fractionation, and electrophoresis, provide some of the most powerful techniques in analytical chemistry and are applied within a number of important application areas, including archaeology, biotechnology, clinical, environmental, food, medical, petroleum, pharmaceutical, polymer and biopolymer research. Beyond serving analytical purposes, separation techniques are also used for preparative and process-scale applications. The scope and power of separation sciences is significantly extended by combination with spectroscopic detection methods (e.g., laser-based approaches, nuclear-magnetic resonance, Raman, chemiluminescence) and particularly, mass spectrometry, to create hyphenated techniques. In addition to exciting new developments in chromatography, such as ultra high-pressure systems, multidimensional separations, and high-temperature approaches, there have also been great advances in hybrid methods combining chromatography and electro-based separations, especially on the micro- and nanoscale. Integrated biological procedures (e.g., enzymatic, immunological, receptor-based assays) can also be part of the overall analytical process.