Two ligands-based europium luminescent coordination polymer, Eu2(PZDC)(PDC)2(H2O)6

IF 2.7 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Inorganica Chimica Acta Pub Date : 2025-02-05 DOI:10.1016/j.ica.2025.122583

Lowik Dewez--Raszka , Sanae Hommada , Yan Suffren , Nathalie Audebrand

引用次数: 0

Abstract

The title compound, europium pyrazine- and pyridine-dicarboxylate hexahydrate, Eu₂(C₆H₂N₂O₄)(C₇H₃NO₄)₂(H₂O)₆, has been synthesized from hydrothermal route. Its crystal structure has been determined from single-crystal X-ray diffraction. The coordination compound is built from tetramers of Eu and pyridine ligands that are linked by pyrazine ligands. These entities form layers that are pillared through hydrogen bonds. The compound possesses a bright red emission due to Eu³⁺ cation even in the presence of vibrators such as water molecules.

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来源期刊

Inorganica Chimica Acta 化学-无机化学与核化学

CiteScore

6.00

自引率

3.60%

发文量

440

审稿时长

35 days

期刊介绍： Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews. Topics covered include: • chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies; • synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs); • reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models; • applications of inorganic compounds, metallodrugs and molecule-based materials. Papers composed primarily of structural reports will typically not be considered for publication.